Up-conversion emission and in vitro cytotoxicity characterization of blue emitting, biocompatible SrTiO3 nanoparticles activated with Tm3+ and Yb3+ ions

作者: R. Pazik , A. Zięcina , B. Poźniak , M. Malecka , L. Marciniak

DOI: 10.1039/C6RA03075K

关键词:

摘要: Functional SrTiO3 nanoparticles activated with a broad concentration range of Tm3+ and Yb3+ ions were obtained utilizing the citric route. The effect sintering temperature optically active co-dopant on structural up-conversion emission properties was studied by using XRD (X-ray powder diffraction) spectroscopic techniques (emission, power dependence, kinetics). particle size verified TEM technique being in 20–90 nm depending annealing temperature. It shown that cross-relaxations contribute to depopulation both 1G4 3H4 levels, whereas some them populate level. These processes are strongly dependent responsible for specific interplay between blue NIR emissions. Extraordinary short decays recorded due relatively high concentrations rare earths, features host matrix, extended surface area contribution non-radiative processes. cytotoxic activity J774.E murine macrophages U2OS human osteosarcoma cells assessed showing SrTiO3:Tm3+/Yb3+ biocompatible can be potentially used further bio-related applications such as implant layers or injectable medical cement ingredients.

参考文章(46)
E. A. Bondarenko, A. A. Skomorokhov, N. I. Kargin, A. S. Gusev, S. M. Ryndya, Study of the photoluminescence properties of crystal phosphors SrTiO3:Pr3+ and SrTiO3:Pr3+, Al Optics and Spectroscopy. ,vol. 118, pp. 729- 734 ,(2015) , 10.1134/S0030400X15050112
G. Nag Bhargavi, Ayush Khare, Luminescence studies of perovskite structured titanates: A review Optics and Spectroscopy. ,vol. 118, pp. 902- 917 ,(2015) , 10.1134/S0030400X15060156
C. R. García, J. Oliva, M. T. Romero, R. Ochoa-Valiente, L. A. Garcia Trujillo, Effect of Eu3 Advances in Materials Science and Engineering. ,vol. 2015, pp. 1- 7 ,(2015) , 10.1155/2015/291230
Robert Pązik, Aleksander Zięcina, Emilia Zachanowicz, Malgorzata Małecka, Blazej Poźniak, Julia Miller, Zbigniew Śniadecki, Natalia Pierunek, Bogdan Idzikowski, Lucyna Mrówczyńska, Anna Ekner‐Grzyb, Rafal J Wiglusz, None, Synthesis, Structural Features, Cytotoxicity, and Magnetic Properties of Colloidal Ferrite Spinel Co1–xNixFe2O4 (0.1 ≤ x ≤ 0.9) Nanoparticles European Journal of Inorganic Chemistry. ,vol. 2015, pp. 4750- 4760 ,(2015) , 10.1002/EJIC.201500668
Sonia Romaniega Piñeiro, Mercedes del Río Merino, Cristina Pérez García, New Plaster Composite with Mineral Wool Fibres from CDW Recycling Advances in Materials Science and Engineering. ,vol. 2015, pp. 1- 9 ,(2015) , 10.1155/2015/854192
J. A. Dawson, X. Li, C. L. Freeman, J. H. Harding, D. C. Sinclair, The application of a new potential model to the rare-earth doping of SrTiO3 and CaTiO3 Journal of Materials Chemistry C. ,vol. 1, pp. 1574- 1582 ,(2013) , 10.1039/C2TC00475E
Farrel W. Lytle, X‐Ray Diffractometry of Low‐Temperature Phase Transformations in Strontium Titanate Journal of Applied Physics. ,vol. 35, pp. 2212- 2215 ,(1964) , 10.1063/1.1702820
Ra�l Garc�a Carrodeguas, Blanca V�zquez Lasa, Julio San Rom�n del Barrio, Injectable acrylic bone cements for vertebroplasty with improved properties Journal of Biomedical Materials Research Part B. ,vol. 68, pp. 94- 104 ,(2004) , 10.1002/JBM.B.20007
F. Güell, R. Solé, Jna. Gavaldà, M. Aguiló, M. Galán, F. Díaz, J. Massons, Upconversion luminescence of Tm3+ sensitized by Yb3+ ions in monoclinic KGd(WO4)2 single crystals Optical Materials. ,vol. 30, pp. 222- 226 ,(2007) , 10.1016/J.OPTMAT.2006.10.028
Marcin Nyk, Rajiv Kumar, Tymish Y. Ohulchanskyy, Earl J. Bergey, Paras N. Prasad, High contrast in vitro and in vivo photoluminescence bioimaging using near infrared to near infrared up-conversion in Tm3+ and Yb3+ doped fluoride nanophosphors. Nano Letters. ,vol. 8, pp. 3834- 3838 ,(2008) , 10.1021/NL802223F