Cyclic olefin addition copolymer, process for production thereof, and retardation film obtained from the copolymer

作者: Toshinori Sakagami , Takashi Tsubouchi , Takashi Imamura

DOI:

关键词:

摘要: A cyclic olefin addition copolymer includes a structural unit (1) derived from compound with C4 alkyl substituent group and (2) C5-12 group, optionally (3) another compound. The novel copolymers according to the present invention are excellent in melt-formability, transparency heat resistance, have low water absorption properties, dielectric constant metal content, suitably used optical parts such as films. Processes produce at high yield small amounts of catalysts.

参考文章(23)
Noboru Yamahara, Akira Iio, Zen Komiya, Kohei Goto, Transparent resin material ,(1988)
Keiji Ohtaka, Ichiro Ohnuki, Tetsuo Yoshizawa, Yasuo Suda, Akio Mihara, Taichi Sugimoto, Hiromichi Yamashita, Toshiaki Sato, Semiconductor photo-sensor and method for manufacturing the same ,(1987)
Michitaka Kaizu, Noboru Oshima, Takashi Imamura, Satoshi Ebata, Process for producing cycloolefin addition polymer ,(2004)
John Lipian, Richard A. Mimna, John C. Fondran, Dmitry Yandulov, Robert A. Shick, Brian L. Goodall, Larry F. Rhodes, John C. Huffman, Addition Polymerization of Norbornene-Type Monomers. High Activity Cationic Allyl Palladium Catalysts Macromolecules. ,vol. 35, pp. 8969- 8977 ,(2002) , 10.1021/MA0209287
W. Kaminsky, A. Bark, M. Arndt, New polymers by homogenous zirconocene/aluminoxane catalysts Macromolecular Symposia. ,vol. 47, pp. 83- 93 ,(1991) , 10.1002/MASY.19910470108
Brian L. Goodall, Saikumar Jayaraman, Larry F. Rhodes, Robert A. Shick, Photoresist compositions comprising polycyclic polymers with acid labile pendant groups ,(1997)
Brian L. Goodall, John C. Fondran, April D. Hennis, Jennifer D. Polley, Ayusman Sen, Andrew Bell, Christine N. Elia, Saikumar Jayaraman, John-Henry Lipian, Larry F. Rhodes, Richard A. Mimna, Catalyst and methods for polymerizing cycloolefins ,(1999)
Tadao Natsuume, Masayoshi Oshima, Teiji Kohara, Yoshikatsu Nishi, Ring-opening hydrogenated copolymer and process for producing the same ,(1988)