Mononuclear indolyldithiocarbamates of SnCl4 and R2SnCl2: Spectroscopic, thermal characterizations and cytotoxicity assays in vitro
作者： Sadaf Khan , Shahab A.A. Nami , K.S. Siddiqi
DOI: 10.1016/J.JORGANCHEM.2007.12.026
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摘要: Abstract Several mononuclear Sn compounds ranging from mono to tetrakisindoline dithiocarbamates have been synthesized and characterized. Various spectroscopic techniques in combination with microanalytical data lead the formation of 1:2 1:4 (Sn:Naindtc) type complexes depending on molar ratio sodium salt indolinedithiocarbamate employed. A symmetrical bidentate coordination has observed all cases as evident by a single sharp band at 1000 cm−1 their IR spectra. The were found adopt an octahedral arrangement around atom 119Sn NMR data. TGA/DSC profile ligand exhibits two-stage thermogram while decompose three steps leading tin-sulfide eventual end product. vitro cytotoxicity butyl phenyl analogues studied against standard human tumor cell lines. also screened for antifungal antibacterial activity E. coli, S. aureus, C. albicans A. flavus. results indicated be active.
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sci-hub.se 参考文章(43)
Subbiah Thirumaran, Kuppukkannu Ramalingam, Mixed ligand complexes involving aminoacid dithiocarbamates, substituted phosphines and nickel(II) Transition Metal Chemistry. ,vol. 25, pp. 60- 62 ,(2000) , 10.1023/A:1007097629965
Leslie Hellerman, Allen H. Neims, Donald S. Coffey, Interaction between Tetraethylthiuram Disulfide and the Sulfhydryl Groups of d-Amino Acid Oxidase and of Hemoglobin Journal of Biological Chemistry. ,vol. 241, pp. 5941- 5948 ,(1966) , 10.1016/S0021-9258(18)96361-1
Peter J. Heard, Main Group Dithiocarbamate Complexes Progress in Inorganic Chemistry. pp. 1- 69 ,(2005) , 10.1002/0471725587.CH1
Rufen Zhang, Jiafeng Sun, Chunlin Ma, Structural chemistry of mononuclear, tetranuclear and hexanuclear organotin(IV) carboxylates from the reaction of di-n-butyltin oxide or diphenyltin oxide with rhodanine-N-acetic acid Journal of Organometallic Chemistry. ,vol. 690, pp. 4366- 4372 ,(2005) , 10.1016/J.JORGANCHEM.2005.07.005
Giuseppina Faraglia, Sergio Sitran, Diego Montagner, Pyrrolidine dithiocarbamates of Pd(II) Inorganica Chimica Acta. ,vol. 358, pp. 971- 980 ,(2005) , 10.1016/J.ICA.2004.09.063
Rohith P. John, A. Sreekanth, V. Rajakannan, T.A. Ajith, M.R. Prathapachandra Kurup, New copper(II) complexes of 2-hydroxyacetophenone N(4)-substituted thiosemicarbazones and polypyridyl co-ligands: structural, electrochemical and antimicrobial studies Polyhedron. ,vol. 23, pp. 2549- 2559 ,(2004) , 10.1016/J.POLY.2004.09.004
Jaroslav Holeček, Antonín Lyčka, Dependence of |1J(119Sn13C)| on the CSnC angle in n-butyltin(IV) compounds Inorganica Chimica Acta. ,vol. 118, ,(1986) , 10.1016/S0020-1693(00)86395-1
T Häupl, T Zimmermann, R Hermann, O Brede, The photoisomerization of spiro[cyclohexadiene-indoline] via an intramolecular charge transfer state Chemical Physics Letters. ,vol. 291, pp. 215- 222 ,(1998) , 10.1016/S0009-2614(98)00584-3
Julio J. Criado, Jose A. Lopez-Arias, Benigno Macias, Luis R. Fernandez-Lago, Juan M. Salas, Au(III) complexes of tris-dithiocarbamate derivatives of α-amino acids: spectroscopic studies, thermal behaviour and antibacterial activity Inorganica Chimica Acta. ,vol. 193, pp. 229- 235 ,(1992) , 10.1016/S0020-1693(00)80357-6
D.C. Menezes, F.T. Vieira, G.M. de Lima, A.O. Porto, M.E. Cortés, J.D. Ardisson, T.E. Albrecht-Schmitt, Tin(IV) complexes of pyrrolidinedithiocarbamate: synthesis, characterisation and antifungal activity. European Journal of Medicinal Chemistry. ,vol. 40, pp. 1277- 1282 ,(2005) , 10.1016/J.EJMECH.2005.07.008