Proton Magnetic Resonance Study of Crystalline Potassium Trisoxalatorhodium(III) Hydrate
作者： A. L. Porte , H. S. Gutowsky , G. M. Harris
DOI: 10.1063/1.1731617
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摘要: The broad‐line proton magnetic resonance spectrum of crystalline potassium trisoxalatorhodium(III) hydrate, K3Rh(C2O4)34½H2O, has been investigated in the temperature range 77°K—330°K. at 77°K indicates that some protons crystal are not present water crystallization and an analysis this same compound should be formulated as K6[Rh(C2O4)3][Rh(C2O4)2(HC2O4)(OH)]8H2O. This formula is inconsistent with chemical reactions undergoes, it explains properties which satisfactorily accounted for by previously accepted K3[Rh(C2O4)3]412H2O. absorption 318°K substantiates also can grouped into least three sets, molecules different sets having degrees mobility. data indicate ``monohydrate,'' K3Rh(C2O4)3H2O, probably K6[Rh(C2...
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