Preparation of mesoporous Ag-containing TiO 2 heterojunction film and its photocatalytic property

作者: QY Wang , JL Qiao , XY Cui , JS Zhong , YB Xu

DOI: 10.1007/S11051-015-2941-5

关键词:

摘要: Mesoporous Ag/TiO2 heterojunction films (Ag-MTHF) with enhanced photocatalytic activity were synthesized by a three-step approach including an electrochemical anodization technique followed successive ionic layer adsorption and reaction (SILAR) solvothermal methods. The distribution of Ag nanoparticles on the inner structure mesoporous TiO2 film was confirmed field emission scanning electron (FE-SEM) transmission microscopes (TEM). formation progress novel nanojunction average diameter 17 nm illuminated. formed between largely degradation methyl orangey (MO), corresponding mechanism proposed.

参考文章(19)
Yi-Feng Lin, Kuo-Lun Tung, Yu-Sheng Tzeng, Jian-Hua Chen, Kai-Shiun Chang, Rapid atmospheric plasma spray coating preparation and photocatalytic activity of macroporous titania nanocrystalline membranes Journal of Membrane Science. ,vol. 389, pp. 83- 90 ,(2012) , 10.1016/J.MEMSCI.2011.10.018
Ali Akbar Ashkarran, Seyed Mahyad Aghigh, Mona kavianipour, Neda Jalali Farahani, Visible light photo-and bioactivity of Ag/TiO2 nanocomposite with various silver contents Current Applied Physics. ,vol. 11, pp. 1048- 1055 ,(2011) , 10.1016/J.CAP.2011.01.042
Frédéric Sauvage, Dehong Chen, Pascal Comte, Fuzhi Huang, Leo-Philipp Heiniger, Yi-Bing Cheng, Rachel A. Caruso, Michael Graetzel, Dye-sensitized solar cells employing a single film of mesoporous TiO2 beads achieve power conversion efficiencies over 10%. ACS Nano. ,vol. 4, pp. 4420- 4425 ,(2010) , 10.1021/NN1010396
Qingyao Wang, Xiuchun Yang, Xuelai Wang, Min Huang, Junwei Hou, Synthesis of N-doped TiO2 mesosponge by solvothermal transformation of anodic TiO2 nanotubes and enhanced photoelectrochemical performance Electrochimica Acta. ,vol. 62, pp. 158- 162 ,(2012) , 10.1016/J.ELECTACTA.2011.12.009
Zhigang Xiong, Jizhen Ma, Wun Jern Ng, T. David Waite, X.S. Zhao, Silver-modified mesoporous TiO2 photocatalyst for water purification Water Research. ,vol. 45, pp. 2095- 2103 ,(2011) , 10.1016/J.WATRES.2010.12.019
Qingyao Wang, Xiuchun Yang, Dan Liu, Jianfu Zhao, Fabrication, characterization and photocatalytic properties of Ag nanoparticles modified TiO2 NTs Journal of Alloys and Compounds. ,vol. 527, pp. 106- 111 ,(2012) , 10.1016/J.JALLCOM.2012.02.180
Guidong Yang, Zheng Jiang, Huahong Shi, Tiancun Xiao, Zifeng Yan, Preparation of highly visible-light active N-doped TiO2 photocatalyst Journal of Materials Chemistry. ,vol. 20, pp. 5301- 5309 ,(2010) , 10.1039/C0JM00376J
AKIRA FUJISHIMA, KENICHI HONDA, Electrochemical Photolysis of Water at a Semiconductor Electrode Nature. ,vol. 238, pp. 37- 38 ,(1972) , 10.1038/238037A0
Pascal Hartmann, Doh-Kwon Lee, Bernd M. Smarsly, Juergen Janek, Mesoporous TiO2: Comparison of Classical Sol−Gel and Nanoparticle Based Photoelectrodes for the Water Splitting Reaction ACS Nano. ,vol. 4, pp. 3147- 3154 ,(2010) , 10.1021/NN1004765
Kiyoung Lee, Doohun Kim, Poulomi Roy, Indhumati Paramasivam, Balaji Ishwarrao Birajdar, Erdmann Spiecker, Patrik Schmuki, Anodic Formation of Thick Anatase TiO2 Mesosponge Layers for High-Efficiency Photocatalysis Journal of the American Chemical Society. ,vol. 132, pp. 1478- 1479 ,(2010) , 10.1021/JA910045X