Structural and functional analogues of the active sites of the [Fe]-, [NiFe]-, and [FeFe]-hydrogenases.

作者: Cédric Tard , Christopher J. Pickett

DOI: 10.1021/CR800542Q

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摘要: This article sets out to review the chemistry relating synthesis of structural and functional analogues three classes hydrogenases. has grown explosively over last 10 or so years since first X-ray structures [NiFe]- [FeFe]-hydrogenase systems were published. There are now some 400 papers covering aspects, with majority these associated di-iron system. As much emphasized in earlier

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