摘要: Miniemulsions are specially formulated heterophase systems consisting of stable nanodroplets in a continuous phase. The narrowly size distributed 50 to 500 nm can be prepared by shearing system containing oil, water, surfactant, and an osmotic pressure agent which is insoluble the Since each regarded as batch reactor, whole variety reactions carried out starting from miniemulsions clearly extending profile classical emulsion polymerization. This articles gives overview about mechanism formation polymerizations reviews current standing field for both synthesis new polymers dispersed hybrid systems.
springer.com
core.ac.uk
mpg.de
springerlink.com参考文章(124)
Krzysztof Matyjaszewski, Jian Qiu, Nicolay V. Tsarevsky, Bernadette Charleux, Atom transfer radical polymerization of n-butyl methacrylate in an aqueous dispersed system: A miniemulsion approach Journal of Polymer Science Part A. ,vol. 38, pp. 4724- 4734 ,(2000) , 10.1002/1099-0518(200012)38:1+<4724::AID-POLA120>3.0.CO;2-Q
C. Farcet, M. Lansalot, R. Pirri, J. P. Vairon, B. Charleux, Polystyrene-block-poly(butyl acrylate) and polystyrene-block-poly[(butyl acrylate)-co-styrene] block copolymers prepared via controlled free-radical miniemulsion polymerization using degenerative iodine transfer Macromolecular Rapid Communications. ,vol. 21, pp. 921- 926 ,(2000) , 10.1002/1521-3927(20000801)21:13<921::AID-MARC921>3.0.CO;2-0
Juan A. Alduncin, Jacqueline Forcada, Jose M. Asua, Miniemulsion Polymerization Using Oil-Soluble Initiators Macromolecules. ,vol. 27, pp. 2256- 2261 ,(1994) , 10.1021/MA00086A041
C.S. Chern, T.J. Chen, Y.C. Liou, Miniemulsion polymerization of styrene in the presence of a water-insoluble blue dye Polymer. ,vol. 39, pp. 3767- 3777 ,(1998) , 10.1016/S0032-3861(97)10347-0
Werner Lauterborn, Claus-Dieter Ohl, Cavitation bubble dynamics Ultrasonics Sonochemistry. ,vol. 4, pp. 65- 75 ,(1997) , 10.1016/S1350-4177(97)00009-6
Klaus Tauer, Harmin Müller, Carsten Schellenberg, Lutz Rosengarten, Evaluation of heterophase polymerizations by means of reaction calorimetry Colloids and Surfaces A: Physicochemical and Engineering Aspects. ,vol. 153, pp. 143- 151 ,(1999) , 10.1016/S0927-7757(98)00436-1
W.I. Higuchi, Jagdish Misra, Physical Degradation of Emulsions Via the Molecular Diffusion Route and the Possible Prevention Thereof Journal of Pharmaceutical Sciences. ,vol. 51, pp. 459- 466 ,(1962) , 10.1002/JPS.2600510514
M. Postel, J. G. Riess, J. G. Weers, Fluorocarbon Emulsions the Stability Issue Artificial Cells, Blood Substitutes, and Biotechnology. ,vol. 22, pp. 991- 1005 ,(1994) , 10.3109/10731199409138797
K. Fontenot, F. J. Schork, Batch polymerization of methyl methacrylate in mini/macroemulsions Journal of Applied Polymer Science. ,vol. 49, pp. 633- 655 ,(1993) , 10.1002/APP.1993.070490410
R. C. Dewald, L. H. Hart, W. F. Carroll, PVC miniemulsion polymerization. I. Origin of droplet families Journal of Polymer Science: Polymer Chemistry Edition. ,vol. 22, pp. 2923- 2930 ,(1984) , 10.1002/POL.1984.170221115