Mossbauer study on photochemistry of ferrocene isolated in low- temperature matrix
作者： Y. Einaga , Y. Yamada , T. Tominaga
DOI: 10.1007/BF02033981
关键词:
摘要: Unstable novel species produced by photolysis of ferrocene (Cp2Fe) isolated in low-temperature matrix were studied means the57Fe Mossbauer spectroscopy. On the UV-irradiation of57Fe-enriched co-condensed with CCl4 N2 (20 K), unknown high spin ferrous (I.S.=0.90±0.01 mm/s, Q.S=1.94±0.02 mm/s) as well ferricinium ion [Cp2Fe]+ (I.S.=0.52±0.01 Q.S.=0.0 mm/s). annealing, these photoproducts disappeared to reform reverse reaction matrix. The mechanisms photochemical discussed.
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