[BH3C(NO2)3]−: The First Room‐Temperature Stable (Trinitromethyl)borate
作者： Guillaume Bélanger-Chabot , Martin Rahm , Ralf Haiges , Karl O. Christe
关键词:
摘要: The first stable (trinitromethyl)borate anion [BH3C(NO2)3]- was synthesized and structurally characterized. BH3 group in provides a significant increase stability compared to the previously studied BCl3 analog. [Na(glyme)2]+, PNP+, PPh4+ salts of were successfully isolated characterized by NMR vibrational spectroscopy. PNP+ salt characterized, confirming theor. predicted B-C connectivity. [on SciFinder(R)]
core.ac.uk
chalmers.se
sci-hub.se 参考文章(32)
Michael Göbel, Thomas M. Klapötke, Potassium-, Ammonium-, Hydrazinium-, Guanidinium-, Aminoguanidinium-, Diaminoguanidinium-, Triaminoguanidinium- and Melaminiumnitroformate – Synthesis, Characterization and Energetic Properties Zeitschrift für anorganische und allgemeine Chemie. ,vol. 633, pp. 1006- 1017 ,(2007) , 10.1002/ZAAC.200700114
G.S. Hammond, W.D. Emmons, C.O. Parker, B.M. Graybill, J.H. Waters, M.F. Hawthorne, Silver salt alkylation reactions and the preparation of polynitroalkanes Tetrahedron. ,vol. 19, pp. 177- 195 ,(1963) , 10.1016/S0040-4020(63)80054-X
LLOYD A. KAPLAN, MORTIMER J. KAMLET, Michael Additions of Nitroform. I. Some Co-products in the Reaction with Methyl Acrylate1a Journal of Organic Chemistry. ,vol. 27, pp. 780- 785 ,(1962) , 10.1021/JO01050A022
K. V. Titova, E. I. Kolmakova, V. Ya. Rosolovskii, Reactions of BCl3 with salts of trinitromethane Russian Chemical Bulletin. ,vol. 26, pp. 1822- 1825 ,(1977) , 10.1007/BF00924367
J. A. Montgomery, M. J. Frisch, J. W. Ochterski, G. A. Petersson, A complete basis set model chemistry. VII. Use of the minimum population localization method Journal of Chemical Physics. ,vol. 112, pp. 6532- 6542 ,(2000) , 10.1063/1.481224
Ralf Haiges, Jerry A. Boatz, Ashwani Vij, Michael Gerken, Stefan Schneider, Thorsten Schroer, Karl O. Christe, Polyazide Chemistry: Preparation and Characterization of Te(N3)4 and [P(C6H5)4]2[Te(N3)6] and Evidence for [N(CH3)4][Te(N3)5] Angewandte Chemie. ,vol. 42, pp. 5847- 5851 ,(2003) , 10.1002/ANIE.200352680
Jane S. Murray, Tore Brinck, Peter Politzer, Relationships of molecular surface electrostatic potentials to some macroscopic properties principles and practice of constraint programming. ,vol. 204, pp. 289- 299 ,(1996) , 10.1016/0301-0104(95)00297-9
Rosendo Valero, José R. B. Gomes, Donald G. Truhlar, Francesc Illas, Good performance of the M06 family of hybrid meta generalized gradient approximation density functionals on a difficult case: CO adsorption on MgO(001). Journal of Chemical Physics. ,vol. 129, pp. 124710- 124710 ,(2008) , 10.1063/1.2982923
Aleksandr V. Marenich, Christopher J. Cramer, Donald G. Truhlar, Universal solvation model based on solute electron density and on a continuum model of the solvent defined by the bulk dielectric constant and atomic surface tensions. Journal of Physical Chemistry B. ,vol. 113, pp. 6378- 6396 ,(2009) , 10.1021/JP810292N
Betsy M Rice, Sharmila V Pai, Jennifer Hare, Predicting heats of formation of energetic materials using quantum mechanical calculations Combustion and Flame. ,vol. 118, pp. 445- 458 ,(1999) , 10.1016/S0010-2180(99)00008-5