The Synthesis of Tricyclo [4. 2. 2. 02, 5] Deca-3, 7, 9-Trienes and Related Derivatives Via the Kolbe Oxidation Route
作者： H. H. Westberg , R. N. Warrener
DOI: 10.1080/00397917208081640
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摘要: Abstract The Koloe oxidation of cis-dicarboxylic acids is a convenient method for clafin synthesis 1,2,3. In an earlier communication 1 one us reported the Tryicyclo [4.2.2.02,5] deca-3,7,9-triane (Nenitzescu's hydrocarbon) by this method. view interest in (CH)10 energy surface, any entry at C10H10 level immediately malcas & wide range ring structure potentially available. 4 For reason we have chosen to concentrate on tricyclo[4.2.2.02,5] deca-3,5,7-triane system and now report results series compounds containing various functional groups which prove be stable under reaction conditions. These include phosphine oxide35, cyclic ether 3g, nitrile1, ester1, vinyl bromide, vincinal dibromide, methoxy, ketone epoxide group (See table).
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