Structure, photochemistry and magnetic properties of tetrahydrogenated Schiff base chromium(III) complexes.
作者： Bin Liu , Jie Chai , SiSi Feng , BinSheng Yang
DOI: 10.1016/J.SAA.2015.01.012
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摘要: Abstract Four mononuclear chromium(III) complexes [Cr(L(1))(en)]Br0.3Cl0.7 (1), [Cr(L(1))(pr)]Cl (2), [Cr(L(2))(en)]ClO4 (3), [Cr(L(2))(pr)]Cl (4) along with one dinuclear μ-methoxo [Cr(μ-OMe)(L1)]2 (5) were synthesized (en = 1,2-ethanediamine, pr = 1,3-diaminopropane H2L(1) = Tetrahydrosalen = H2[H4]salen = N,N′-bis(2-hydroxybenzyl)-1,2-ethanediamine, H2L(2) = Tetrahydrosalpr = H2[H4]salpr = N,N′-bis(2-hydroxybenzyl)-1,3-diaminopropane). The competitive reactions in the presence of EDTA carried out and first-order rate constants k(1) = (5.2 ± 0.2) × 10−3 h−1
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