Electronic states of a C70 monolayer on the surface of Ag(111).
作者： Peng Wang , Liang Meng , Xiao-Bo Wang , Yan-Jun Li , Chun-Qi Sheng
DOI: 10.1088/0953-8984/23/39/395002
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摘要: We have investigated the electronic states of a C70?monolayer on surface Ag(111) (1?ML C70/Ag(111)) using synchrotron radiation photoelectron spectroscopy and soft x-ray absorption techniques. The experimental data exhibit metallic properties at least 2.6?e? charge transfer per C70 molecule. screening effect structure is remarkable; it greatly reduces or even eliminates on-site Hubbard energy. work functions multilayer monolayer are determined as 4.53?eV 4.52?eV respectively. energy levels align with Fermi level substrate, shift vacuum caused by adsorption negligible. Potassium doping indicates that 1?ML C70/Ag(111) can still accommodate about nine electrons sample remains any level.
sci-hub.se 参考文章(33)
Mats Nyberg, Yi Luo, Luciano Triguero, Lars G. M. Pettersson, Hans Ågren, Core-hole effects in x-ray-absorption spectra of fullerenes Physical Review B. ,vol. 60, pp. 7956- 7960 ,(1999) , 10.1103/PHYSREVB.60.7956
Jun Sakai, Tetsuya Taima, Toshihiro Yamanari, Kazuhiro Saito, Annealing effect in the sexithiophene:C70 small molecule bulk heterojunction organic photovoltaic cells Solar Energy Materials and Solar Cells. ,vol. 93, pp. 1149- 1153 ,(2009) , 10.1016/J.SOLMAT.2009.02.007
Ku-Ding Tsuei, Jih-Young Yuh, Chyuan-Tsyr Tzeng, Ren-Yu Chu, Shih-Chun Chung, King-Lung Tsang, Photoemission and photoabsorption study of C 60 adsorption on Cu(111) surfaces Physical Review B. ,vol. 56, pp. 15412- 15420 ,(1997) , 10.1103/PHYSREVB.56.15412
K.-D. Tsuei, P.D. Johnson, Charge transfer and a new image state of C60 on Cu(1 1 1) surface studied by inverse photoemission Solid State Communications. ,vol. 101, pp. 337- 341 ,(1997) , 10.1016/S0038-1098(96)00590-X
T. Pardini, C. Cepek, R. Larciprete, L. Sangaletti, S. Pagliara, R. Gotter, L. Floreano, A. Verdini, A. Morgante, F. Parmigiani, A. Goldoni, Metallic phases of a C70 single layer adsorbed on Cu(1 1 1) doped with sodium Surface Science. ,vol. 532, pp. 892- 897 ,(2003) , 10.1016/S0039-6028(03)00179-1
Leia Stirling, Karen Willcox, Philip Ferguson, Dava Newman, Kinetics and Kinematics for Translational Motions in Microgravity During Parabolic Flight Aviation, Space, and Environmental Medicine. ,vol. 80, pp. 522- 531 ,(2009) , 10.3357/ASEM.2356.2009
C. Silien, P.A. Thiry, Y. Caudano, HREELS study of the intercalation of K atoms in C60 monolayers Surface Science. ,vol. 558, pp. 174- 180 ,(2004) , 10.1016/J.SUSC.2004.03.065
T. R. Ohno, Y. Chen, S. E. Harvey, G. H. Kroll, J. H. Weaver, R. E. Haufler, R. E. Smalley, C60 bonding and energy-level alignment on metal and semiconductor surfaces. Physical Review B. ,vol. 44, pp. 13747- 13755 ,(1991) , 10.1103/PHYSREVB.44.13747
A. Goldoni, C. Cepek, R. Larciprete, L. Sangaletti, S. Pagliara, L. Floreano, R. Gotter, A. Verdini, A. Morgante, Y. Luo, M. Nyberg, C70 adsorbed on Cu(111): Metallic character and molecular orientation Journal of Chemical Physics. ,vol. 116, pp. 7685- 7690 ,(2002) , 10.1063/1.1467346
Woei Wu Pai, H. T. Jeng, C.-M. Cheng, C.-H. Lin, Xudong Xiao, Aidi Zhao, Xieqiu Zhang, Geng Xu, X. Q. Shi, M. A. Van Hove, C.-S. Hsue, K.-D. Tsuei, Optimal electron doping of a C60 monolayer on Cu(111) via interface reconstruction. Physical Review Letters. ,vol. 104, pp. 036103- ,(2010) , 10.1103/PHYSREVLETT.104.036103