Facile synthesis of a mesoporous alumina and its application as a support of Ni-based autothermal reforming catalysts
作者： Soodeh Sepehri , Mehran Rezaei , Gabriella Garbarino , Guido Busca
DOI: 10.1016/J.IJHYDENE.2015.12.122
关键词:
摘要: Abstract Mesoporous nanocrystalline γ-Al 2 O 3 powder with high specific surface area (>220 m /g) was prepared by a “solid state” method and employed as the support for nickel catalysts. Ni catalysts supported on this alumina were investigated in autothermal reforming of methane. The characterized XRD, BET, DR-UV-Vis, TPR SEM techniques before after reaction. effect experimental conditions, such temperature, space velocity, steam to carbon (S/C) oxygen (O/C) ratio catalytic performance Catalyst 25 wt.% content revealed methane conversion (around 86% at 700 °C). activity is reduced calcination 800 °C, which results lower formation bulk aluminate spinel.
core.ac.uk
elsevier.com
sci-hub.se 参考文章(29)
Guido Busca, Structural, Surface, and Catalytic Properties of Aluminas Advances in Catalysis. ,vol. 57, pp. 319- 404 ,(2014) , 10.1016/B978-0-12-800127-1.00003-5
M.V. Phanikrishna Sharma, Jale F. Akyurtlu, Ates Akyurtlu, Autothermal reforming of isobutanol over promoted nickel xerogel catalysts for hydrogen production International Journal of Hydrogen Energy. ,vol. 40, pp. 13368- 13378 ,(2015) , 10.1016/J.IJHYDENE.2015.07.113
Suk Yong Jung, Dong Geon Ju, Eun Ji Lim, Soo Chool Lee, Byung Wook Hwang, Jae Chang Kim, None, Study of sulfur-resistant Ni–Al-based catalysts for autothermal reforming of dodecane International Journal of Hydrogen Energy. ,vol. 40, pp. 13412- 13422 ,(2015) , 10.1016/J.IJHYDENE.2015.08.044
Soodeh Sepehri, Mehran Rezaei, Preparation of Highly Active Nickel Catalysts Supported on Mesoporous Nanocrystallineγ-Al2O3for Methane Autothermal Reforming Chemical Engineering & Technology. ,vol. 38, pp. 1637- 1645 ,(2015) , 10.1002/CEAT.201400566
Z.L. Zhang, V.A. Tsipouriari, A.M. Efstathiou, X.E. Verykios, Reforming of Methane with Carbon Dioxide to Synthesis Gas over Supported Rhodium Catalysts: I. Effects of Support and Metal Crystallite Size on Reaction Activity and Deactivation Characteristics Journal of Catalysis. ,vol. 158, pp. 51- 63 ,(1996) , 10.1006/JCAT.1996.0005
Alina Tirsoaga, Diana Visinescu, Bogdan Jurca, Adelina Ianculescu, Oana Carp, Eco-friendly combustion-based synthesis of metal aluminates MAl2O4 (M = Ni, Co) Journal of Nanoparticle Research. ,vol. 13, pp. 6397- 6408 ,(2011) , 10.1007/S11051-011-0392-1
Baiyu Huang, Calvin H. Bartholomew, Stacey J. Smith, Brian F. Woodfield, Facile solvent-deficient synthesis of mesoporous γ-alumina with controlled pore structures Microporous and Mesoporous Materials. ,vol. 165, pp. 70- 78 ,(2013) , 10.1016/J.MICROMESO.2012.07.052
Hamidreza Arandiyan, Junhua Li, Lei Ma, S.M. Hashemnejad, M.Z. Mirzaei, Jinghuan Chen, Huazhen Chang, Caixia Liu, Chizhong Wang, Liang Chen, Methane reforming to syngas over LaNixFe1−xO3 (0 ≤ x ≤ 1) mixed-oxide perovskites in the presence of CO2 and O2 Journal of Industrial and Engineering Chemistry. ,vol. 18, pp. 2103- 2114 ,(2012) , 10.1016/J.JIEC.2012.06.004
Guido Busca, Vincenzo Lorenzelli, Vicente Sanchez Escribano, Preparation, solid-state characterization, and surface chemistry of high-surface-area nickel-aluminum (NixAl2-2xO3-2x) mixed oxides Chemistry of Materials. ,vol. 4, pp. 595- 605 ,(1992) , 10.1021/CM00021A019
Jiang Li, Yubai Pan, Changshu Xiang, Qiming Ge, Jingkun Guo, Low temperature synthesis of ultrafine α-Al2O3 powder by a simple aqueous sol–gel process Ceramics International. ,vol. 32, pp. 587- 591 ,(2006) , 10.1016/J.CERAMINT.2005.04.015