Effect of inclusions on cratering behavior in TiNi shape memory alloys irradiated with a low-energy, high-current electron beam

作者: L.L. Meisner , A.B. Markov , D.I. Proskurovsky , V.P. Rotshtein , G.E. Ozur

DOI: 10.1016/J.SURFCOAT.2016.06.036

关键词:

摘要: Abstract Irradiation of TiNi shape memory alloys with a microsecond low-energy (10–30 keV), high-current (10–25 kA) electron beam in surface melting modes induces microcrater formation, which limits the practical use this method modification. Potential centers crater formation are inclusions, inherent to alloys. However, there is limited information about their role and nature phenomenon as applied In paper, microstructural identification inclusions was carried out commercial (VIM) precision using TEM/SAED/EDS methods. The topographical features microcraters formed by single-pulse irradiation samples near threshold B2 matrix phase were identified. It found SEM/EDS-analysis, that mainly nucleated on titanium oxycarbide TiC(O) (commercial alloy) oxide Ti 4 Ni 2 O (precision inclusions; both cases, central region enriched oxygen. gradient capillary forces melt mass transfer (Marangoni effect), determine microcraters, analyzed. shown thermocapillary play an insignificant role, while chemicapillary induced decreasing tension due its oxygen enrichment can be sufficiently large produce microcraters.

参考文章(64)
Vladimir Rotshtein, Yury Ivanov, Alexey Markov, Surface Treatment of Materials with Low-Energy, High-Current Electron Beams Materials Surface Processing by Directed Energy Techniques. pp. 205- 240 ,(2006) , 10.1016/B978-008044496-3/50007-1
M.F. MAITZ, Surface modification of Ti–Ni alloys for biomedical applications Shape Memory Alloys for Biomedical Applications. pp. 173- 193 ,(2009) , 10.1533/9781845695248.1.173
S. SHABALOVSKAYA, J. VAN HUMBEECK, Biocompatibility of Nitinol for biomedical applications Shape Memory Alloys for Biomedical Applications. pp. 194- 233 ,(2009) , 10.1533/9781845695248.1.194
Edmund Kugler Storms, The Refractory carbides Academic. ,(1967)
Gennadii Andreevich Mesyats, Dimitri Illich Proskurovsky, None, Pulsed Electrical Discharge in Vacuum ,(1989)
Hong Yong Sohn, Milton E. Wadsworth, Rate Processes of Extractive Metallurgy ,(1979)
Kensuke Uemura, Takeshi Tsubouchi, Takehisa Mori, Atsushi Okawa, Manufacturing method for medical equipment for reducing platelet adhesion of a surface in contact with blood ,(2011)
Jianxin Zou, Kemin Zhang, Chuang Dong, Ying Qin, Shengzhi Hao, Thierry Grosdidier, Selective surface purification via crater eruption under pulsed electron beam irradiation Applied Physics Letters. ,vol. 89, pp. 041913- ,(2006) , 10.1063/1.2234306
R. Novakovic, E. Ricci, Surface and transport properties of Ni–Ti liquid alloys Journal of Alloys and Compounds. ,vol. 452, pp. 167- 173 ,(2008) , 10.1016/J.JALLCOM.2007.01.176
A. Coda, S. Zilio, D. Norwich, F. Sczerzenie, Characterization of Inclusions in VIM/VAR NiTi Alloys Journal of Materials Engineering and Performance. ,vol. 21, pp. 2572- 2577 ,(2012) , 10.1007/S11665-012-0366-1