Hetero-assembly of a Li4Ti5O12 nanosheet and multi-walled carbon nanotube nanocomposite for high-performance lithium and sodium ion batteries

作者: Y. Tian , Z. L. Wu , G. B. Xu , L. W. Yang , J. X. Zhong

DOI: 10.1039/C6RA25651A

关键词:

摘要: A nanocomposite composed of crystalline Li4Ti5O12 (LTO) nanosheets and multi-walled carbon nanotubes (denoted as LTO/MWCNTs) is prepared for lithium/sodium storage via a facile hetero-assembly process driven by the screening effect electrostatic repulsion following thermal treatment. The morphology microstructure characterizations reveal that LTO are embedded in highly porous electrically conductive MWCNT network, thereby producing robust inner-connected architectures. Owing to improved electron ion transportation during electrochemical reaction rendered unique integrated architecture two-dimensional MWCNTs, exhibits excellent lithium sodium performances. For batteries, anode delivers reversible capacity 149.7 mA h g−1 at 10C after 500 cycles. As it has 82 5C. LTO/MWCNT great potential high-performance material dual applications batteries.

参考文章(40)
Ivana Hasa, Roberta Verrelli, Jusef Hassoun, Transition metal oxide-carbon composites as conversion anodes for sodium-ion battery Electrochimica Acta. ,vol. 173, pp. 613- 618 ,(2015) , 10.1016/J.ELECTACTA.2015.05.107
Chao Wu, Peter Kopold, Yuan-Li Ding, Peter A. van Aken, Joachim Maier, Yan Yu, Synthesizing Porous NaTi2(PO4)3 Nanoparticles Embedded in 3D Graphene Networks for High-Rate and Long Cycle-Life Sodium Electrodes ACS Nano. ,vol. 9, pp. 6610- 6618 ,(2015) , 10.1021/ACSNANO.5B02787
G.B. Xu, L.W. Yang, X.L. Wei, J.W. Ding, J.X. Zhong, P.K. Chu, Highly-crystalline ultrathin gadolinium doped and carbon-coated Li4Ti5O12 nanosheets for enhanced lithium storage Journal of Power Sources. ,vol. 295, pp. 305- 313 ,(2015) , 10.1016/J.JPOWSOUR.2015.06.131
Liang Zhao, Hui-Lin Pan, Yong-Sheng Hu, Hong Li, Li-Quan Chen, Spinel lithium titanate (Li4Ti5O12) as novel anode material for room-temperature sodium-ion battery Chinese Physics B. ,vol. 21, pp. 028201- ,(2012) , 10.1088/1674-1056/21/2/028201
Lin Gao, Shaohui Li, Dekang Huang, Yan Shen, Mingkui Wang, Porous Li4Ti5O12–TiO2 nanosheet arrays for high-performance lithium-ion batteries Journal of Materials Chemistry. ,vol. 3, pp. 10107- 10113 ,(2015) , 10.1039/C5TA01054C
Guodong Du, Brad R. Winton, Israa M. Hashim, Neeraj Sharma, Konstantin Konstantinov, M. V. Reddy, Zaiping Guo, Mass production of Li4Ti5O12 with a conductive network via in situ spray pyrolysis as a long cycle life, high rate anode material for lithium ion batteries RSC Advances. ,vol. 4, pp. 38568- 38574 ,(2014) , 10.1039/C4RA05178E
Jun Liu, Kepeng Song, Peter A. van Aken, Joachim Maier, Yan Yu, Self-supported Li4Ti5O12-C nanotube arrays as high-rate and long-life anode materials for flexible Li-ion batteries. Nano Letters. ,vol. 14, pp. 2597- 2603 ,(2014) , 10.1021/NL5004174
Jun Ming, Yingqiang Wu, Yancun Yu, Fengyu Zhao, Steaming multiwalled carbon nanotubes via acid vapour for controllable nanoengineering and the fabrication of carbon nanoflutes Chemical Communications. ,vol. 47, pp. 5223- 5225 ,(2011) , 10.1039/C1CC10525F
Jinyun Liu, Nan Li, Matthew D. Goodman, Hui Gang Zhang, Eric S. Epstein, Bo Huang, Zeng Pan, Jinwoo Kim, Jun Hee Choi, Xingjiu Huang, Jinhuai Liu, K. Jimmy Hsia, Shen J. Dillon, Paul V. Braun, Mechanically and chemically robust sandwich-structured C@Si@C nanotube array Li-ion battery anodes. ACS Nano. ,vol. 9, pp. 1985- 1994 ,(2015) , 10.1021/NN507003Z
Mi Ru Jo, Ki Min Nam, Youngmin Lee, Kyeongse Song, Joon T. Park, Yong-Mook Kang, Phosphidation of Li4Ti5O12 nanoparticles and their electrochemical and biocompatible superiority for lithium rechargeable batteries Chemical Communications. ,vol. 47, pp. 11474- 11476 ,(2011) , 10.1039/C1CC15320J