Remarkably Stable Chalcogen(II) Dications
作者： Caleb D. Martin , Christine M. Le , Paul J. Ragogna
DOI: 10.1021/JA9073968
关键词:
摘要: Air-stable, chalcogen-centered dications have been synthesized and comprehensively characterized. These represent the first diiminopyridine (DIMPY) complexes of chalcogens as well single nonmetallic (sulfur) complex this ubiquitous ligand. Their stability under ambient conditions is a distinct contrast to other highly charged main-group cations.
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