Gd(OTf)3-(Bmim)(PF6): A Novel and Recyclable Catalytic System for the Synthesis of Quinolines

作者: Jian-Long Wu , Rei-Sheu Hou , Huey-Min Wang , Iou-Jiun Kang , Ling-Ching Chen

DOI: 10.1002/JCCS.200900128

关键词:

摘要: A mild and efficient route for the synthesis of quinolines polycyclic utilizing Gadolinium triflate (Gd(OTf) 3 ) as a novel catalyst via Friedlander annulation in ionic liquid 1-n-butyl-3-methylimidazolium hexafluorophosphate [Bmim][PF 6 ] under conditions was described.

参考文章(49)
Martyn J. Earle, Paul B. McCormac, Kenneth R. Seddon, Diels–Alder reactions in ionic liquids. A safe recyclable alternative to lithium perchlorate–diethyl ether mixtures Green Chemistry. ,vol. 1, pp. 23- 25 ,(1999) , 10.1039/A808052F
Xinying Zhang, Xuesen Fan, Jianji Wang, Yanzhen Li, A Novel Preparation of 4-Phenylquinoline Derivatives in Ionic Liquids Journal of the Chinese Chemical Society. ,vol. 51, pp. 1339- 1342 ,(2004) , 10.1002/JCCS.200400194
Sandra Einloft, Fernanda K. Dietrich, Roberto F. De Souza, Jairton Dupont, Selective two-phase catalytic ethylene dimerization by NiII complexes/AlEtCl2 dissolved in organoaluminate ionic liquids Polyhedron. ,vol. 15, pp. 3257- 3259 ,(1996) , 10.1016/0277-5387(96)00048-4
Claude de Bellefon, Eric Pollet, Pierre Grenouillet, Molten salts (ionic liquids) to improve the activity, selectivity and stability of the palladium catalysed Trost–Tsuji C–C coupling in biphasic media Journal of Molecular Catalysis A-chemical. ,vol. 145, pp. 121- 126 ,(1999) , 10.1016/S1381-1169(99)00032-1
Doug W Morrison, David C Forbes, James H Davis, Base-promoted reactions in ionic liquid solvents. The Knoevenagel and Robinson annulation reactions Tetrahedron Letters. ,vol. 42, pp. 6053- 6055 ,(2001) , 10.1016/S0040-4039(01)01228-X
A. Walser, T. Flynn, R. Ian Fryer, Nucleophilic displacement of aromatic fluorine. Part IV. Quinolinoquinolines and benzochromenoquinolines Journal of Heterocyclic Chemistry. ,vol. 12, pp. 737- 741 ,(1975) , 10.1002/JHET.5570120424
Robert H. Grubbs, Sukbok Chang, Recent advances in olefin metathesis and its application in organic synthesis Tetrahedron. ,vol. 54, pp. 4413- 4450 ,(1998) , 10.1016/S0040-4020(97)10427-6
Jeffrey A. Boon, Joseph A. Levisky, J. Lloyd Pflug, John S. Wilkes, Friedel-Crafts reactions in ambient-temperature molten salts Journal of Organic Chemistry. ,vol. 51, pp. 480- 483 ,(1986) , 10.1021/JO00354A013