Polycaprolactone–Polyaniline Blend: Effects of the Addition of Cysteine on the Structural and Molecular Properties

作者: Sergio Kogikoski Jr , Michelle S Liberato , Irina M Factori , Emerson R da Silva , Cristiano LP Oliveira

DOI: 10.1021/ACS.JPCC.6B10011

关键词:

摘要: Organic molecule conjugates usually arrange themselves into complex multiphase systems that are sensitive to processing and local chemical environment. Moreover, these able self-assemble at different scales, varying from nano- macroscale. In addition, intermolecular interactions introduce structural variations in the molecular packing large-scale ordering, which directly affects physicochemical properties of materials. Herein, we study synthesis polymer blends based on poly(e)-caprolactone (PCL) with polyaniline (PANI) doped amino acid N-acetyl-l-cysteine (NAC). Samples were prepared either through solution casting or via electrospinning methods. The materials characterized regarding their morphological, structural, length scales. From results obtained, relationship between changes blend NAC concentrations was determined. Deep details have been unveiled by using ...

参考文章(55)
Hengliang Hu, Douglas L. Dorset, Crystal structure of poly(iε-caprolactone) Macromolecules. ,vol. 23, pp. 4604- 4607 ,(1990) , 10.1021/MA00223A017
Soma Khanra, Thiago Cipriano, Thomas Lam, Tommi A White, Eudes E Fileti, Wendel A Alves, Suchismita Guha, None, Self-Assembled Peptide-Polyfluorene Nanocomposites for Biodegradable Organic Electronics Advanced Materials Interfaces. ,vol. 2, pp. 1500265- ,(2015) , 10.1002/ADMI.201500265
ET Kang, KG Neoh, KL Tan, POLYANILINE: A POLYMER WITH MANY INTERESTING INTRINSIC REDOX STATES Progress in Polymer Science. ,vol. 23, pp. 277- 324 ,(1998) , 10.1016/S0079-6700(97)00030-0
H. Bittiger, R. H. Marchessault, W. D. Niegisch, Crystal structure of poly-ε-caprolactone Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry. ,vol. 26, pp. 1923- 1927 ,(1970) , 10.1107/S0567740870005198
J. Romanova, J. Petrova, A. Tadjer, N. Gospodinova, Polyaniline-water interactions: A theoretical investigation with the polarisable continuum model Synthetic Metals. ,vol. 160, pp. 1050- 1054 ,(2010) , 10.1016/J.SYNTHMET.2010.02.025
Alessandro Chiolerio, Sergio Bocchini, Samuele Porro, Inkjet Printed Negative Supercapacitors: Synthesis of Polyaniline-Based Inks, Doping Agent Effect, and Advanced Electronic Devices Applications Advanced Functional Materials. ,vol. 24, pp. 3375- 3383 ,(2014) , 10.1002/ADFM.201303371
S. S. Soni, G. Brotons, M. Bellour, T. Narayanan, A. Gibaud, Quantitative SAXS analysis of the P123/water/ethanol ternary phase diagram. Journal of Physical Chemistry B. ,vol. 110, pp. 15157- 15165 ,(2006) , 10.1021/JP062159P
Taimoor H. Qazi, Ranjana Rai, Aldo R. Boccaccini, Tissue engineering of electrically responsive tissues using polyaniline based polymers: a review. Biomaterials. ,vol. 35, pp. 9068- 9086 ,(2014) , 10.1016/J.BIOMATERIALS.2014.07.020
Maria Ann Woodruff, Dietmar Werner Hutmacher, The return of a forgotten polymer—Polycaprolactone in the 21st century Progress in Polymer Science. ,vol. 35, pp. 1217- 1256 ,(2010) , 10.1016/J.PROGPOLYMSCI.2010.04.002