Influence of stereoregularity on the photoinitiated electrical conductivity of poly (3-alkylthiophenes)

作者: C. Sentein , B. Mouanda , A. Rosilio , C. Rosilio

DOI: 10.1016/S0379-6779(97)80049-5

关键词:

摘要: Abstract Several kinds of synthesis methods leading to regie and stereo chemical control polymer architecture also polymers derived from oligomers possessing internal symmetry or containing suitably spaced alkyl chains have been performed. The different structures studied in relation their electrical conductivity behaviour. Doping has photoinitiated with optically dissociative materials (triarylsulfonium salts) which were incorporated the basic poly(3-alkylthiophene) into spinning solution. Conditions light exposure (wavelength range, dose) concentration photodopant used optimized order enhance its thermal stability. High-resolution conducting patterns realized by microlithography techniques. Their possible use microelectronics is investigated.

参考文章(35)
Terje A Skotheim, None, Handbook of conducting polymers CRC Press. ,(1986)
John Crank, The mathematics of diffusion ,(1956)
D. Braun, G. Gustafsson, D. McBranch, A. J. Heeger, Electroluminescence and electrical transport in poly(3‐octylthiophene) diodes Journal of Applied Physics. ,vol. 72, pp. 564- 568 ,(1992) , 10.1063/1.351834
G. Gustafsson, O. Inganäs, J.O. Nilsson, B. Liedberg, Thermal undoping in poly(3-alkylthiophenes) Synthetic Metals. ,vol. 26, pp. 297- 309 ,(1988) , 10.1016/0379-6779(88)90245-7
Helmut Neugebauer, Gerhard Nauer, Adolf Neckel, Gerard Tourillon, Francis Garnier, Philippe Lang, In situ investigations of the 3-methylthiophene polymer with attenuated total reflection Fourier transform infrared spectroscopy The Journal of Physical Chemistry. ,vol. 88, pp. 652- 654 ,(1984) , 10.1021/J150648A004
M. Angelopoulos, J. M. Shaw, W.-S. Huang, R. D. Kaplan, In-Situ Radiation Induced Doping Molecular Crystals and Liquid Crystals. ,vol. 189, pp. 221- 225 ,(1990) , 10.1080/00268949008037234
A. O. Patil, A. J. Heeger, Fred Wudl, Optical properties of conducting polymers Chemical Reviews. ,vol. 88, pp. 183- 200 ,(1988) , 10.1021/CR00083A009
J.T. Lopez-Navarrete, G. Zerbi, On the stability of doped conducting polymers: electrostatic contributions and sterical effects Chemical Physics Letters. ,vol. 175, pp. 125- 129 ,(1990) , 10.1016/0009-2614(90)85529-L
Mohamed S.A. Abdou, Steven Holdcroft, Solid-state photochemistry of π-conjugated poly(3-alkylthiophenes) Canadian Journal of Chemistry. ,vol. 73, pp. 1893- 1901 ,(1995) , 10.1139/V95-234
Takakazu Yamamoto, Ken-ichi Sanechika, Akio Yamamoto, Preparation and characterization of poly(thienylene)s. Bulletin of the Chemical Society of Japan. ,vol. 56, pp. 1497- 1502 ,(1983) , 10.1246/BCSJ.56.1497