Solvatochromism of non-polar complexes
作者： Elaine S. Dodsworth , A.B.P. Lever
DOI: 10.1016/0010-8545(90)80095-B
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摘要: Abstract : The Solvatochromism of various, formally non-polar, complexes is analysed using the McRae equation. solvatochromism dinuclear species, M(CO)42(ppm). (Molybdenum, Tungsten; bpm = 2,2'bipyrimidine) found to result from individual dipoles each half molecule interacting with solvent. This contrary previously published explanations. non-polar Ru(DTBSq)3 (DTBSq 3,5-di-t-butylseniquinone) also found, unexpectedly, correlate polar terms McRae's Possible reasons for this are discussed.
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sci-hub.se 参考文章(23)
Wilfred Louis Florio Armarego, Douglas Dalzell Perrin, D. R Perrin, Purification of laboratory chemicals ,(1966)
Noel S. Bayliss, The Effect of the Electrostatic Polarization of the Solvent on Electronic Absorption Spectra in Solution The Journal of Chemical Physics. ,vol. 18, pp. 292- 296 ,(1950) , 10.1063/1.1747621
Wolfgang Kaim, Stephan Kohlmann, Sylvia Ernst, Barbara Olbrich-Deussner, Christian Bessenbacher, Andreas Schulz, What determines the solvatochromism of metal-to-ligand charge transfer transitions? A demonstration involving 17 tungsten carbonyl complexes Journal of Organometallic Chemistry. ,vol. 321, pp. 215- 226 ,(1987) , 10.1016/0022-328X(87)85041-6
M. Shoup, B. Hall, R. R. Ruminski, Synthesis, characterization, and solvatochromic studies of group 6 metal carbonyls bound to the bridging ligand 2,3-bis(2-pyridyl)pyrazine (dpp) Inorganic Chemistry. ,vol. 27, pp. 200- 203 ,(1988) , 10.1021/IC00274A041
Steven J. Milder, Solvent effects on the long-axis intraligand transition of tris(2,2'-bipyridine)ruthenium(2+) and related compounds Inorganic Chemistry. ,vol. 28, pp. 868- 872 ,(1989) , 10.1021/IC00304A014
David M. Manuta, Alistair J. Lees, Solvatochromism of the metal to ligand charge-transfer transitions of zerovalent tungsten carbonyl complexes Inorganic Chemistry. ,vol. 25, pp. 3212- 3218 ,(1986) , 10.1021/IC00238A025
Wolfgang Kaim, Sylvia Ernst, Stephan Kohlmann, Mono- and binuclear molybdenum carbonyl complexes with charge-transfer absorptions in the near IR. Polyhedron. ,vol. 5, pp. 445- 449 ,(1986) , 10.1016/S0277-5387(00)84948-7
Douglas J. Gordon, Richard F. Fenske, Theoretical study of o-quinone complexes of iron Inorganic Chemistry. ,vol. 21, pp. 2916- 2923 ,(1982) , 10.1021/IC00138A002
Douglas J. Gordon, Richard F. Fenske, Theoretical study of o-quinone complexes of chromium and vanadium Inorganic Chemistry. ,vol. 21, pp. 2907- 2915 ,(1982) , 10.1021/IC00138A001
Kathy J. Moore, John D. Petersen, Synthesis, characterization and photochemistry of some monometallic and bimetallic 2,2′-bipyrimidine complexes of chromium and tungsten carbonyls Polyhedron. ,vol. 2, pp. 279- 284 ,(1983) , 10.1016/S0277-5387(00)83914-5