Synthesis, characterization, and molecular structures of Ni(II) and Cd(II) complexes derived from dithiophosphonate
作者： Alireza Banaei , Afshin Saadat , Mina Mohammad Goli , Patrick McArdle , Eslam Pourbasheer
DOI: 10.1002/HC.21345
关键词:
摘要: Two novel dithiophosphonate ligands, HS2P(p-C6H4OMe)(OCH2CH2CH(CH3)2) (1) and HS2P(p-C6H4OMe)(OCH(CH3)2) (2), were synthesized characterized by multinuclear (1H, 31P, 13C) NMR, infrared spectroscopy as well elemental analysis. The reactions of 1 2 with NiCl2·6H2O Cd(NO3)2·4H2O in methanol led to complexes 3 4. single crystal X-ray structures 4 showed tetracoordinated structure square planar geometry for the nickel complex, while it pentacoordinated distorted square-pyramid environment cadmium complex.
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