Kinetics of Enzyme-Catalysed Reactions in Water-in-Oil Microemulsions

作者: Christopher Oldfield , Cristina Otero , Maria L. Rua , Antonio Ballesteros

DOI: 10.1016/B978-0-444-89046-7.50034-5

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摘要: Abstract In water-in-oil microemulsions the aqueous sub-phase is present as a monodispersion of spherical droplets. A theoretical treatment (C. Oldfield (1990) Biochem. J 247 15–22 and (1991) J. Chem. Soc. Faraday Trans I 87 2607–2612) shows how rates enzyme-catalysed reactions involving water-soluble substrates can be expected to depend on droplet size concentration rate exchange solutes between this article theory briefly restated, with examples experimental systems which behave predicted by theory.

参考文章(6)
Karel Martinek, A.V. Levashov, N.L. Klyachko, V.I. Pantin, I.V. Berezin, The principles of enzymes stabilization Biochimica et Biophysica Acta (BBA) - Enzymology. ,vol. 657, pp. 277- 294 ,(1981) , 10.1016/0005-2744(81)90151-0
Raymond M. D. VERHAERT, Riet HILHORST, Marian VERMUE, Tjeerd J. SCHAAFSMA, Cees VEEGER, Description of enzyme kinetics in reversed micelles 1. Theory FEBS Journal. ,vol. 187, pp. 59- 72 ,(1990) , 10.1111/J.1432-1033.1990.TB15277.X
Paul D.I. Fletcher, Robert B. Freedman, Jeremy Mead, Christopher Oldfield, Brian H. Robinson, Reactivity of α-chymotrypsin in water-in-oil microemulsions Colloids and Surfaces. ,vol. 10, pp. 193- 203 ,(1984) , 10.1016/0166-6622(84)80020-7
Paul D.I. Fletcher, Gareth D. Rees, Brian H. Robinson, Robert B. Freedman, Kinetic properties of α-chymotrypsin in water-in-oil microemulsions: studies with a variety of substrates and microemulsion systems Biochimica et Biophysica Acta. ,vol. 832, pp. 204- 214 ,(1985) , 10.1016/0167-4838(85)90333-4
Christopher Oldfield, Exchange concept in water-in-oil microemulsions: consequences for ‘slow’ chemical reactions Journal of the Chemical Society, Faraday Transactions. ,vol. 87, pp. 2607- 2612 ,(1991) , 10.1039/FT9918702607