Facile Fabrication of Ordered Component-Tunable Heterobimetallic Self-Assembly Nanosheet for Catalyzing “Click” Reaction

作者: Xiang Gu , Sa Bi , Linna Guo , Yaqing Zhao , Tiesheng Li

DOI: 10.1021/ACSOMEGA.7B00364

关键词:

摘要: How to maximize the number of desirable active sites on surface catalyst and minimize promoting undesirable side reactions is currently an important research topic. In this study, a new way based synergism achieve successful fabrication ordered heterobimetallic self-assembled monolayer (denoted as BMSAM) with controlled composition excellent orientation metals in was developed. BMSAM consisting phenanthroline Schiff-base groups prepared, its novel (Cu Pd) anchored silicon Si-Fmp-Cu-Pd fixed position fabricated characterized by UV, cyclic voltammetry, Raman, X-ray photoelectron spectroscopy (XPS), scanning electron microscopy (SEM), diffraction (XRD), inductively coupled plasma atomic emission (ICP-AES), water-drop contact angle (WDCA) analyses. The effects i...

参考文章(221)
Rafael Chinchilla, Carmen Nájera, Chemicals from Alkynes with Palladium Catalysts Chemical Reviews. ,vol. 114, pp. 1783- 1826 ,(2014) , 10.1021/CR400133P
Hui Liu, Tiesheng Li, Xiaoxia Xue, Wenjian Xu, Yangjie Wu, The mechanism of a self-assembled Pd(ferrocenylimine)–Si compound-catalysed Suzuki coupling reaction Catalysis Science & Technology. ,vol. 6, pp. 1667- 1676 ,(2016) , 10.1039/C5CY01341K
Ranjan Jana, Tejas P. Pathak, Matthew S. Sigman, Advances in transition metal (Pd, Ni, Fe)-catalyzed cross-coupling reactions using alkyl-organometallics as reaction partners. Chemical Reviews. ,vol. 111, pp. 1417- 1492 ,(2011) , 10.1021/CR100327P
Zhihua Fu, Tiesheng Li, Xiaohang He, Jie Liu, Wenjian Xu, Yangjie Wu, Cyclopalladated ferrocenylimine functionalized polymer brushes film and its mechanism investigation of heterogeneous catalysis Journal of Molecular Catalysis A: Chemical. ,vol. 395, pp. 293- 299 ,(2014) , 10.1016/J.MOLCATA.2014.08.038
Mehul B. Thathagar, Jurriaan Beckers, Gadi Rothenberg, Copper-catalyzed Suzuki cross-coupling using mixed nanocluster catalysts. Journal of the American Chemical Society. ,vol. 124, pp. 11858- 11859 ,(2002) , 10.1021/JA027716+
Christian Girard, Esra Önen, Marie Aufort, Sophie Beauvière, Edmond Samson, Jean Herscovici, Reusable polymer-supported catalyst for the [3+2] Huisgen cycloaddition in automation protocols. Organic Letters. ,vol. 8, pp. 1689- 1692 ,(2006) , 10.1021/OL060283L
Gonghu Li, Eduardo M. Sproviero, William R. McNamara, Robert C. Snoeberger, Robert H. Crabtree, Gary W. Brudvig, Victor S. Batista, Reversible Visible-Light Photooxidation of an Oxomanganese Water-Oxidation Catalyst Covalently Anchored to TiO2 Nanoparticles† Journal of Physical Chemistry B. ,vol. 114, pp. 14214- 14222 ,(2010) , 10.1021/JP908925Z
Qian Zhang, Fan Yang, Yangjie Wu, Palladium-catalyzed ortho-acylation of 2-aryl pyridine derivatives using arylmethyl amines as new acyl sources Chemical Communications. ,vol. 49, pp. 6837- 6839 ,(2013) , 10.1039/C3CC42106F