Direct Synthesis of Powdery Inorganic Electride [Ca24Al28O64]4+(e−)4and Determination of Oxygen Stoichiometry
作者： Satoru Matsuishi , Takatoshi Nomura , Masahiro Hirano , Katsuaki Kodama , Shin-ichi Shamoto
DOI: 10.1021/CM9007987
关键词:
摘要: We found a method for direct synthesis of C12A7 electride [Ca24Al28O64]4+(e−)4 powders from Ca12Al14O33 (C12A7), CaAl2O4 (CA), and Ca metal; CA were synthesized CaCO3 Al2O3. The chemical composition the agrees with that lacking encaged O2− ions, electron concentration was almost equal to theoretical value positive charge density cage skeleton.
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sci-hub.se 参考文章(23)
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