Synthesis of vinyl sulfides by copper-catalyzed decarboxylative C-S cross-coupling.
作者： Sadananda Ranjit , Zhongyu Duan , Pengfei Zhang , Xiaogang Liu
DOI: 10.1021/OL101729K
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摘要: A novel method for the synthesis of vinyl sulfides by decarboxylative cross-coupling arylpropiolic acids with thiols using copper(I) salts as catalysts has been developed. In presence CuI and Cs2CO3, a variety reacted to afford corresponding in good excellent yields high stereoselectivity Z-isomers.
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