Crossed-beam scattering of F+CD4→DF+CD3(νNK): The integral cross sections
作者： Jingang Zhou , Jim J. Lin , Weicheng Shiu , Shih-Chieh Pu , Kopin Liu
DOI: 10.1063/1.1587112
关键词:
摘要: The title reaction was investigated in a crossed-beam experiment. A (2+1) resonance-enhanced multiphon ionization technique used to interrogate the internal-state distributions of CD3 product at three different collision energies. Only ν2 (umbrella) mode excitation observed. Its distribution changes from monotonically declined low energy slightly inverted one higher energy. Although rotational excitations were small, strong preference for K=0 found, indicative dominance tumbling rotation motion product. vibration-resolved functions also measured ν2=0–3. barrier 0.5 kcal/mol deduced.
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