Measures of Covalency in Transition‐Metal Chlorides
作者： R. Bersohn , R. G. Shulman
DOI: 10.1063/1.1727924
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摘要: The bonding between transition‐metal ions and chlorine is largely ionic. It has been known that the small degree of covalency in chloride crystals could be measured by transferred magnetic hyperfine interactions with nuclei. Here we show Townes Dailey theory allows one to derive from nuclear quadrupole coupling these crystals. In few cases where both electric have at same nucleus, calculated two methods agrees rather well. Both kinds experiment indicate importance π d orbitals as well σ bonding.
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