Highly durable phosphonated graphene oxide doped polyvinylidene fluoride (PVDF) composite membranes

作者: Aygun Cali , Yavuz Yağızatlı , Alpay Sahin , İrfan Ar

DOI: 10.1016/J.IJHYDENE.2020.01.092

关键词:

摘要: Abstract The polyvinylidene fluoride (PVDF) drew great attention over time amongst the hydrocarbon polymer membranes because of its high C–F chemical bond strength. In this work is to increase proton conductivity PVDF by doping phosphonated graphene oxide structure and investigate improvement membrane. Different amounts additive (0.5%, 1% 1.5% w/w) were doped on purpose synthesizing exchange composite membranes. Characterization tests, i.e, water uptake, swelling properties, ion capacity, synthesized investigated. electrochemical impedance analysis results vary between 0.0224 S cm-1 for 0.5% (PVDF/0.5PGO) 0.0867 PVDF/1.5GO power density values PVDF/1.5PGO PVDF/0.5GO are 48 mW cm−2 28 mW cm−2 at 0.6 V 100% relative humidity 80 °C. experimental demonstrate importance into

参考文章(61)
Chenyi Wang, Bin Shen, Chang Xu, Xiaoyan Zhao, Jian Li, Side-chain-type poly(arylene ether sulfone)s containing multiple quaternary ammonium groups as anion exchange membranes Journal of Membrane Science. ,vol. 492, pp. 281- 288 ,(2015) , 10.1016/J.MEMSCI.2015.05.060
Huijuan Bai, Yifan Li, Haoqin Zhang, Huiling Chen, Wenjia Wu, Jingtao Wang, Jindun Liu, Anhydrous proton exchange membranes comprising of chitosan and phosphorylated graphene oxide for elevated temperature fuel cells Journal of Membrane Science. ,vol. 495, pp. 48- 60 ,(2015) , 10.1016/J.MEMSCI.2015.08.012
Nayibe Guerrero Moreno, Myriam Cisneros Molina, Dominic Gervasio, Juan Francisco Pérez Robles, Approaches to polymer electrolyte membrane fuel cells (PEMFCs) and their cost Renewable & Sustainable Energy Reviews. ,vol. 52, pp. 897- 906 ,(2015) , 10.1016/J.RSER.2015.07.157
Christian Beauger, Guillaume Lainé, Alain Burr, Aurélie Taguet, Belkacem Otazaghine, Improvement of Nafion®-sepiolite composite membranes for PEMFC with sulfo-fluorinated sepiolite. Journal of Membrane Science. ,vol. 495, pp. 392- 403 ,(2015) , 10.1016/J.MEMSCI.2015.08.014
Agnieszka Iwan, Marek Malinowski, Grzegorz Pasciak, Polymer fuel cell components modified by graphene: Electrodes, electrolytes and bipolar plates Renewable & Sustainable Energy Reviews. ,vol. 49, pp. 954- 967 ,(2015) , 10.1016/J.RSER.2015.04.093
Leila Ahmadian-Alam, Mehdi Kheirmand, Hossein Mahdavi, Preparation, characterization and properties of PVDF-g-PAMPS/PMMA-co-PAMPS/silica nanoparticle as a new proton exchange nanocomposite membrane Chemical Engineering Journal. ,vol. 284, pp. 1035- 1048 ,(2016) , 10.1016/J.CEJ.2015.09.048
Bingxin Zhou, Hongting Pu, Haiyan Pan, Decheng Wan, Proton exchange membranes based on semi-interpenetrating polymer networks of Nafion® and poly(vinylidene fluoride) via radiation crosslinking International Journal of Hydrogen Energy. ,vol. 36, pp. 6809- 6816 ,(2011) , 10.1016/J.IJHYDENE.2011.02.115
A. Mokrini, M.A. Huneault, Proton exchange membranes based on PVDF/SEBS blends Journal of Power Sources. ,vol. 154, pp. 51- 58 ,(2006) , 10.1016/J.JPOWSOUR.2005.04.021