Li4Ti5O12/reduced graphite oxide nano-hybrid material for high rate lithium-ion batteries

作者: Hyun-Kyung Kim , Seong-Min Bak , Kwang-Bum Kim

DOI: 10.1016/J.ELECOM.2010.10.018

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摘要: Abstract A spinel Li 4 Ti 5 O 12 nanoplatelet/reduced graphite oxide nano-hybrid was successfully synthesized by a two-step microwave-assisted solvothermal reaction and heat treatment. The in the hybrid could deliver discharge capacity of 154 mAhg − 1 at 1 C-rate, 128 mAhg -1 50 C-rate 101 mAhg 100 C-rate. It demonstrated promising potential as an anode material Li-ion battery with excellent rate capability good cycling.

参考文章(13)
Tsutomu Ohzuku, Atsushi Ueda, Norihiro Yamamoto, Zero‐Strain Insertion Material of Li [ Li1 / 3Ti5 / 3 ] O 4 for Rechargeable Lithium Cells Journal of The Electrochemical Society. ,vol. 142, pp. 1431- 1435 ,(1995) , 10.1149/1.2048592
Chunhai Jiang, Masaki Ichihara, Itaru Honma, Haoshen Zhou, Effect of particle dispersion on high rate performance of nano-sized Li4Ti5O12 anode Electrochimica Acta. ,vol. 52, pp. 6470- 6475 ,(2007) , 10.1016/J.ELECTACTA.2007.04.070
Martin Winter, Jürgen O. Besenhard, Michael E. Spahr, Petr Novák, Insertion Electrode Materials for Rechargeable Lithium Batteries Advanced Materials. ,vol. 10, pp. 725- 763 ,(1998) , 10.1002/(SICI)1521-4095(199807)10:10<725::AID-ADMA725>3.0.CO;2-Z
A. S. Prakash, P. Manikandan, K. Ramesha, M. Sathiya, J-M. Tarascon, A. K. Shukla, Solution-Combustion Synthesized Nanocrystalline Li4Ti5O12 As High-Rate Performance Li-Ion Battery Anode Chemistry of Materials. ,vol. 22, pp. 2857- 2863 ,(2010) , 10.1021/CM100071Z
Katsuhiko Naoi, Shuichi Ishimoto, Yusaku Isobe, Shintaro Aoyagi, High-rate nano-crystalline Li4Ti5O12 attached on carbon nano-fibers for hybrid supercapacitors Journal of Power Sources. ,vol. 195, pp. 6250- 6254 ,(2010) , 10.1016/J.JPOWSOUR.2009.12.104
Gregory J. Wilson, Aaron S. Matijasevich, David R. G. Mitchell, Jamie C. Schulz, Geoffrey D. Will, Modification of TiO2 for enhanced surface properties: finite Ostwald ripening by a microwave hydrothermal process. Langmuir. ,vol. 22, pp. 2016- 2027 ,(2006) , 10.1021/LA052716J
Zhifeng Du, Xiaoming Yin, Ming Zhang, Quanyi Hao, Yanguo Wang, Taihong Wang, In situ synthesis of SnO2/graphene nanocomposite and their application as anode material for lithium ion battery Materials Letters. ,vol. 64, pp. 2076- 2079 ,(2010) , 10.1016/J.MATLET.2010.06.039
Yong Zhou, Qiaoliang Bao, Lena Ai Ling Tang, Yulin Zhong, Kian Ping Loh, Hydrothermal Dehydration for the “Green” Reduction of Exfoliated Graphene Oxide to Graphene and Demonstration of Tunable Optical Limiting Properties Chemistry of Materials. ,vol. 21, pp. 2950- 2956 ,(2009) , 10.1021/CM9006603
Junjie Huang, Zhiyu Jiang, The preparation and characterization of Li4Ti5O12/carbon nano-tubes for lithium ion battery Electrochimica Acta. ,vol. 53, pp. 7756- 7759 ,(2008) , 10.1016/J.ELECTACTA.2008.05.031
Yanyu Liang, Dongqing Wu, Xinliang Feng, Klaus Müllen, Dispersion of Graphene Sheets in Organic Solvent Supported by Ionic Interactions Advanced Materials. ,vol. 21, pp. 1679- 1683 ,(2009) , 10.1002/ADMA.200803160