Synthesis of Pd/C Catalysts: Approaches to Regulating the Structure of Active Sites toward Achieving High Selectivity in Hydrogenation of Organic Compounds

作者: R. M. Mironenko , O. B. Belskaya , V. A. Likholobov

DOI: 10.1134/S1070363220030299

关键词:

摘要: The methods for regulating the physicochemical and catalytic properties of Pd/C compositions by varying their synthesis conditions were reviewed. effect nature carbon support, composition palladium precursor its reduction conditions, addition a second active metal on formation sites, dispersion, electronic state, in practically important hydrogenation reactions was demonstrated using results obtained authors. These data may be useful development catalysts exhibiting high activity selectivity polyfunctional organic compounds.

参考文章(71)
Robert Schlögl, Carbon in Catalysis Advances in Catalysis. ,vol. 56, pp. 103- 185 ,(2013) , 10.1016/B978-0-12-420173-6.00002-4
Dang Sheng Su, Carbon Nanotubes and Related Carbonaceous Structures Nanomaterials in Catalysis, First Edition. pp. 331- 374 ,(2012) , 10.1002/9783527656875.CH9
Elaine A. Gelder, S. David Jackson, C. Martin Lok, A Study of Nitrobenzene Hydrogenation Over Palladium/Carbon Catalysts Catalysis Letters. ,vol. 84, pp. 205- 208 ,(2002) , 10.1023/A:1021432104496
Pengfei Zhang, Huiyuan Zhu, Sheng Dai, Porous Carbon Supports: Recent Advances with Various Morphologies and Compositions Chemcatchem. ,vol. 7, pp. 2788- 2805 ,(2015) , 10.1002/CCTC.201500368
Meenakshisundaram Sankar, Nikolaos Dimitratos, Peter J. Miedziak, Peter P. Wells, Christopher J. Kiely, Graham J. Hutchings, Designing bimetallic catalysts for a green and sustainable future Chemical Society Reviews. ,vol. 41, pp. 8099- 8139 ,(2012) , 10.1039/C2CS35296F
E. Auer, A. Freund, J. Pietsch, T. Tacke, Carbons as supports for industrial precious metal catalysts Applied Catalysis A-general. ,vol. 173, pp. 259- 271 ,(1998) , 10.1016/S0926-860X(98)00184-7
P. GALLEZOT, D. RICHARD, Selective Hydrogenation of α,β-Unsaturated Aldehydes Catalysis Reviews-science and Engineering. ,vol. 40, pp. 81- 126 ,(1998) , 10.1080/01614949808007106
KangCheng Chen, YunXiang Pan, ChangJun Liu, Effect of reduction method on the performance of Pd catalysts supported on activated carbon for the selective oxidation of glucose Science China Chemistry. ,vol. 53, pp. 1598- 1602 ,(2010) , 10.1007/S11426-010-4035-7
Roman M. Mironenko, Olga B. Belskaya, Vladimir I. Zaikovskii, Vladimir A. Likholobov, Effects of the carbon support nature and ruthenium content on the performances of Ru/C catalysts in the liquid-phase hydrogenation of benzaldehyde to benzyl alcohol Monatshefte Fur Chemie. ,vol. 146, pp. 923- 930 ,(2015) , 10.1007/S00706-015-1445-4