Large-scale hydrothermal synthesis and optical properties of Cr2+:ZnS nanocrystals
作者： Chaoyu Li , Haohong Chen , Maxim Ivanov , Tengfei Xie , Jiawei Dai
DOI: 10.1016/J.CERAMINT.2018.04.141
关键词:
摘要: Abstract Cr2+:ZnS is an important mid-infrared laser material, and nanopowders are very for the fabrication of transparent ceramics. In this paper, were synthesized via a hydrothermal method, in which thioacetamide (TAA) was adopted as sulfur source reducing agent to avoid oxidation Cr2+ ions. The influences time [Zn2+]/[TAA] ratio on morphology particle size investigated systematically well reaction mechanism. It believed that orientated attachment Oswald ripening both occurred during reaction, resulted formation bimodal distribution. After calcination under Ar/H2 atmosphere, ions successfully doped into Zn2+ lattice sites, supported by X-ray powder diffraction patterns, absorption photoluminescence spectra products. optical properties similar with those samples obtained thermal diffusion, means they have potential application
sci-hub.se 参考文章(23)
S. B. Qadri, E. F. Skelton, D. Hsu, A. D. Dinsmore, J. Yang, H. F. Gray, B. R. Ratna, Size-induced transition-temperature reduction in nanoparticles of ZnS Physical Review B. ,vol. 60, pp. 9191- 9193 ,(1999) , 10.1103/PHYSREVB.60.9191
H. Nelkowski, G. Grebe, IR-luminescence of ZnS:Cr Journal of Luminescence. ,vol. 1-2, pp. 88- 93 ,(1970) , 10.1016/0022-2313(70)90025-6
Umit Demirbas, Alphan Sennaroglu, Mehmet Somer, Synthesis and characterization of diffusion-doped Cr2+:ZnSe and Fe2+:ZnSe Optical Materials. ,vol. 28, pp. 231- 240 ,(2006) , 10.1016/J.OPTMAT.2004.10.022
J. F. Suyver, S. F. Wuister, J. J. Kelly, A. Meijerink, Synthesis and Photoluminescence of Nanocrystalline ZnS:Mn^(2+) Nano Letters. ,vol. 1, pp. 429- 433 ,(2001) , 10.1021/NL015551H
D V Martyshkin, V V Fedorov, C Kim, I S Moskalev, S B Mirov, Mid-IR random lasing of Cr-doped ZnS nanocrystals Journal of Optics. ,vol. 12, pp. 024005- ,(2010) , 10.1088/2040-8978/12/2/024005
Jinman Huang, Yi Yang, Shanhua Xue, Bai Yang, Shiyong Liu, Jiacong Shen, Photoluminescence and electroluminescence of ZnS:Cu nanocrystals in polymeric networks Applied Physics Letters. ,vol. 70, pp. 2335- 2337 ,(1997) , 10.1063/1.118866
C. Kim, D. V. Martyshkin, V. V. Fedorov, S. B. Mirov, Mid-infrared Cr 2+ :ZnSe random powder lasers Optics Express. ,vol. 16, pp. 4952- 4959 ,(2008) , 10.1364/OE.16.004952
Jiayu Yi, Guoying Feng, Chao Yang, Hong Zhang, Ke Yao, Shouhuan Zhou, 2.18 μm random laser action based on Cr2+:ZnSe nanocrystalline particles Optics Communications. ,vol. 309, pp. 170- 174 ,(2013) , 10.1016/J.OPTCOM.2013.07.010
D.V. Martyshkin, V.V. Fedorov, S.B. Mirov, C. Kim, Middle-infrared random lasing of Cr2+ doped ZnSe, ZnS, CdSe powders, powders imbedded in polymer liquid solutions, and polymer films Optics Communications. ,vol. 282, pp. 2049- 2052 ,(2009) , 10.1016/J.OPTCOM.2009.02.023
R. Pappalardo, R. E. Dietz, Absorption Spectra of Transition Ions in CdS Crystals Physical Review. ,vol. 123, pp. 1188- 1203 ,(1961) , 10.1103/PHYSREV.123.1188