Amidification of poly(styrene-co-maleic anhydride) with amines in tetrahydrofuran solution: A kinetic study

作者: GH Hu , JT Lindt , None

DOI: 10.1007/BF00944831

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摘要: The kinetics of the reaction between a styrene-maleic anhydride copolymer (SMA) and amines was investigated in tetrahydrofuran solution between 0° C and 40° C. This reaction converts the maleic anhydride (MA) into the corresponding amide-acid, while the consecutive reaction of the generated acid with amine forming a diamide or transformation of the acid-amide into the imide was not observed. The amine reactivity follows the order: 1-octylamine>> 1-methyl hexylamine>> 1, 1-dimethyl propylamine or dibutylamine …

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