Fabrication of a novel sandwich-like composite separator with enhanced physical and electrochemical performances for lithium-ion battery
作者： Dazhao Wu , Jinlin He , Mingzu Zhang , Peihong Ni , Xiaofei Li
DOI: 10.1016/J.JPOWSOUR.2015.04.182
关键词:
摘要: In this work, two kinds of composite separators are prepared and used for lithium-ion batteries, which a PP nonwoven/PVdF-HFP/PMMA blending-type separator (CS) sandwich-like nonwoven/PVdF-HFP with the introduction PMMA nanoparticles on surface (nano-CS). The morphology, electrolyte uptake, ionic conductivity electrochemical properties studied by SEM analysis, impedance measurements, charge–discharge cycle C-rate tests, respectively. nano-CS CS(0.2) exhibit similar in uptake (212% 202%, respectively) porosity (77.9% 75.3%, respectively). Nonetheless, shows enhanced thermal stability higher compared commercial separators. Meanwhile, LiFePO4/Li half-cell assembled displays best capacity cyclability especially at high discharge current rate, indicating that is kind promising candidate high-performance batteries.
harvard.edu
elsevier.com
sci-hub.se 参考文章(41)
J.-M. Tarascon, M. Armand, Issues and challenges facing rechargeable lithium batteries Nature. ,vol. 414, pp. 359- 367 ,(2001) , 10.1038/35104644
A. Manuel Stephan, K.S. Nahm, Review on composite polymer electrolytes for lithium batteries Polymer. ,vol. 47, pp. 5952- 5964 ,(2006) , 10.1016/J.POLYMER.2006.05.069
Ki Jae Kim, Jae-Hun Kim, Min-Sik Park, Hyuk Kwon Kwon, Hansu Kim, Young-Jun Kim, Enhancement of electrochemical and thermal properties of polyethylene separators coated with polyvinylidene fluoride-hexafluoropropylene co-polymer for Li-ion batteries Journal of Power Sources. ,vol. 198, pp. 298- 302 ,(2012) , 10.1016/J.JPOWSOUR.2011.09.086
Carlos M. Costa, Maria M. Silva, S. Lanceros-Méndez, Battery separators based on vinylidene fluoride (VDF) polymers and copolymers for lithium ion battery applications RSC Advances. ,vol. 3, pp. 11404- 11417 ,(2013) , 10.1039/C3RA40732B
A GOPALAN, P SANTHOSH, K MANESH, J NHO, S KIM, C HWANG, K LEE, Development of electrospun PVdF-PAN membrane-based polymer electrolytes for lithium batteries Journal of Membrane Science. ,vol. 325, pp. 683- 690 ,(2008) , 10.1016/J.MEMSCI.2008.08.047
Jun-Li Shi, Li-Feng Fang, Hao Li, Hong Zhang, Bao-Ku Zhu, Li-Ping Zhu, Improved thermal and electrochemical performances of PMMA modified PE separator skeleton prepared via dopamine-initiated ATRP for lithium ion batteries Journal of Membrane Science. ,vol. 437, pp. 160- 168 ,(2013) , 10.1016/J.MEMSCI.2013.03.006
Junli Shi, Yonggao Xia, Shaojie Han, Lifeng Fang, Meizi Pan, Xiaoxiong Xu, Zhaoping Liu, Lithium ion conductive Li1.5Al0.5Ge1.5(PO4)3 based inorganic–organic composite separator with enhanced thermal stability and excellent electrochemical performances in 5 V lithium ion batteries Journal of Power Sources. ,vol. 273, pp. 389- 395 ,(2015) , 10.1016/J.JPOWSOUR.2014.09.105
Jingyu Xi, Shaojun Miao, Xiaozhen Tang, Selective Transporting of Lithium Ion by Shape Selective Molecular Sieves ZSM-5 in PEO-Based Composite Polymer Electrolyte Macromolecules. ,vol. 37, pp. 8592- 8598 ,(2004) , 10.1021/MA048849D
Bruno Scrosati, Jürgen Garche, Lithium batteries: Status, prospects and future Journal of Power Sources. ,vol. 195, pp. 2419- 2430 ,(2010) , 10.1016/J.JPOWSOUR.2009.11.048
Shih-Hong Wang, Sheng-Shu Hou, Ping-Lin Kuo, Hsisheng Teng, Poly(ethylene oxide)-co-Poly(propylene oxide)-Based Gel Electrolyte with High Ionic Conductivity and Mechanical Integrity for Lithium-Ion Batteries ACS Applied Materials & Interfaces. ,vol. 5, pp. 8477- 8485 ,(2013) , 10.1021/AM4019115