A new efficient route for the synthesis of 4,4′,6,6′-tetra(azido)azo-1,3,5-triazine
作者： Xiao Tong Li , Sheng Hua Li , Si Ping Pang , Yong Zhong Yu , Yun Jun Luo
DOI: 10.1016/J.CCLET.2007.06.028
关键词:
摘要: Abstract A new method for the synthesis of 4,4′,6,6′-tetra(azido)azo-1,3,5-triazine (TAAT) is described. The key intermediate 4,4′,6,6′-tetra(azido)hydrazo-1,3,5-triazine (TAHT) was synthesized by nucleophilic substitution in case sodium azide as nucleophile. N-Bromosuccinide (NBS) used oxidant to oxidize TAHT a tractable operation under mild reaction condition. target compound TAAT obtained with facile process and high overall yield 81%. structures its intermediates were identified spectroscopic methods.
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