An efficient catalyst of Cu/MIL-101 modified with CeO2 for the conversion of biomass-derived glycerol with aniline to 3-methylindole

作者: Kuixia Ke , Fengliang Wu , Liting Ren , Yanbo Jiao , Na Xing

DOI: 10.1016/J.CATCOM.2019.105896

关键词:

摘要: Abstract An efficient catalyst of Cu/MIL-101 modified with CeO2 for the conversion biomass-derived glycerol aniline to 3-methylindole was constructed yield aimed product up 59%. The characterizations revealed that addition not only improved dispersion Cu particles, but also inhibited sintering active component, meanwhile, number weak acid sites greatly increased, which favorable high selectivity 3-methylindole. Moreover, catalytic reaction mechanism studied in depth, both acetol and 1,2-propanediol were intermediates synthesis

参考文章(36)
Camille Boucher-Jacobs, Kenneth M. Nicholas, Deoxydehydration of polyols. Topics in Current Chemistry. ,vol. 353, pp. 163- 184 ,(2014) , 10.1007/128_2014_537
Wei Sun, Dong-Yan Liu, Hai-Yan Zhu, Lei Shi, Qi Sun, None, A new efficient approach to 3-methylindole: Vapor-phase synthesis from aniline and glycerol over Cu-based catalyst Catalysis Communications. ,vol. 12, pp. 147- 150 ,(2010) , 10.1016/J.CATCOM.2010.08.011
Yanxi Cui, Xiaoshuang Zhou, Qi Sun, Lei Shi, Vapor-phase synthesis of 3-methylindole from glycerol and aniline over zeolites-supported Cu-based catalysts Journal of Molecular Catalysis A-chemical. ,vol. 378, pp. 238- 245 ,(2013) , 10.1016/J.MOLCATA.2013.06.015
Chun Hui Zhou, Heng Zhao, Dong Shen Tong, Lin Mei Wu, Wei Hua Yu, Recent Advances in Catalytic Conversion of Glycerol Catalysis Reviews. ,vol. 55, pp. 369- 453 ,(2013) , 10.1080/01614940.2013.816610
Jana Juan-Alcañiz, Jesús Ferrando-Soria, Ignacio Luz, Pablo Serra-Crespo, Emmanuel Skupien, Vera P. Santos, Emilio Pardo, Francesc X. Llabrés i Xamena, Freek Kapteijn, Jorge Gascon, The oxamate route, a versatile post-functionalization for metal incorporation in MIL-101(Cr): Catalytic applications of Cu, Pd, and Au Journal of Catalysis. ,vol. 307, pp. 295- 304 ,(2013) , 10.1016/J.JCAT.2013.08.001
Zhaoyu WANG, Xiaohui LI, Yue ZHANG, Lei SHI, Qi SUN, Effect of Alkaline-Earth Metal Oxides on Cu/SiO2-Al2O3 Catalyst for Vapor-Phase Synthesis of 3-Methylindole from Glycerol and Aniline Chinese Journal of Catalysis. ,vol. 33, pp. 1139- 1145 ,(2012) , 10.1016/S1872-2067(11)60407-5
Jing LIU, Chunmei LI, Xiaomin HUO, Lei SHI, Qi SUN, Direct Vapor-Phase Synthesis of Indole: Effect of MgO on the Performance of Cu/SiO2 Catalyst Chinese Journal of Catalysis. ,vol. 29, pp. 159- 162 ,(2008) , 10.1016/S1872-2067(08)60022-4
Pawan Siwach, Surander Singh, R K Gupta, Vapor phase alkylation of indole with methanol and dimethylcarbonate over Ni–Mn based ferrospinels Catalysis Communications. ,vol. 10, pp. 1577- 1581 ,(2009) , 10.1016/J.CATCOM.2009.04.019
Weichen Du, Gongzhou Chen, Renfeng Nie, Yingwei Li, Zhaoyin Hou, Highly dispersed Pt in MIL-101: An efficient catalyst for the hydrogenation of nitroarenes Catalysis Communications. ,vol. 41, pp. 56- 59 ,(2013) , 10.1016/J.CATCOM.2013.06.038