Decomposition behaviors of the lignocellulosics as treated by semi-flow hot-compressed water

作者: Masatsugu Takada , Eiji Minami , Shiro Saka

DOI: 10.1016/J.SUPFLU.2017.07.007

关键词:

摘要: Abstract The semi-flow hot-compressed water treatment is expected as a promising technology to convert the lignocellulosics into energy and chemicals. When was treated by two-step (1st stage: 230 °C/10 MPa/15 min, 2nd 270 °C/10 MPa/15 min), its cell wall components can be effectively decomposed. In order understand decomposition behaviors of components, it quite important chemical structure each component. Thus, structures were introduced, for component, pathway proposed. Furthermore, among lignin confirmed not uniformly distributed within wall. Therefore, an importance topochemistry delignification discussed.

参考文章(38)
B. Bennett, E.C. McDonald, J. Howard, Chemicals from forest products by supercritical fluid extraction Fluid Phase Equilibria. ,vol. 10, pp. 337- 344 ,(1983) , 10.1016/0378-3812(83)80048-X
Katsunobu Ehara, Shiro Saka, Haruo Kawamoto, Characterization of the lignin-derived products from wood as treated in supercritical water Journal of Wood Science. ,vol. 48, pp. 320- 325 ,(2002) , 10.1007/BF00831354
William Shu Lai Mok, Michael Jerry Antal, Uncatalyzed solvolysis of whole biomass hemicellulose by hot compressed liquid water Industrial & Engineering Chemistry Research. ,vol. 31, pp. 1157- 1161 ,(1992) , 10.1021/IE00004A026
Gaurav Mishra, Shiro Saka, Kinetic behavior of liquefaction of Japanese beech in subcritical phenol. Bioresource Technology. ,vol. 102, pp. 10946- 10950 ,(2011) , 10.1016/J.BIORTECH.2011.08.126
B. J. Fergus, D. A. I. Goring, The Location of Guaiacyl and Syringyl Lignins in Birch Xylem Tissue Holzforschung. ,vol. 24, pp. 113- 117 ,(1970) , 10.1515/HFSG.1970.24.4.113
Yu Nakahara, Kazuchika Yamauchi, Shiro Saka, MALDI-TOF/MS analyses of decomposition behavior of beech xylan as treated by semi-flow hot-compressed water Journal of Wood Science. ,vol. 60, pp. 225- 231 ,(2014) , 10.1007/S10086-014-1396-0
Nathan Mosier, Charles Wyman, Bruce Dale, Richard Elander, YY Lee, Mark Holtzapple, Michael Ladisch, Features of promising technologies for pretreatment of lignocellulosic biomass. Bioresource Technology. ,vol. 96, pp. 673- 686 ,(2005) , 10.1016/J.BIORTECH.2004.06.025
Jerry W. King, Keerthi Srinivas, Multiple unit processing using sub- and supercritical fluids Journal of Supercritical Fluids. ,vol. 47, pp. 598- 610 ,(2009) , 10.1016/J.SUPFLU.2008.08.010
Natthanon Phaiboonsilpa, Pramila Tamunaidu, Shiro Saka, Two-step hydrolysis of nipa (Nypa fruticans) frond as treated by semi-flow hot-compressed water Holzforschung. ,vol. 65, pp. 659- 666 ,(2011) , 10.1515/HF.2011.046
Xin Lu, Kazuchika Yamauchi, Natthanon Phaiboonsilpa, Shiro Saka, Two-step hydrolysis of Japanese beech as treated by semi-flow hot-compressed water Journal of Wood Science. ,vol. 55, pp. 367- 375 ,(2009) , 10.1007/S10086-009-1040-6