Organic reactions in strong alkalis-I : Fission of ethylenic acids (the varrentrapp reaction)
作者： R.G. Ackman , Patrick Linstead , B.J. Wakefield , B.C.L. Weedon
DOI: 10.1016/0040-4020(60)80031-2
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摘要: Abstract On treatment with molten potassium hydroxide, ethylenic acids are converted initially into a mixture of isomers, by reversible migration the double bond in both directions along chain, and finally saturated acid, two fewer carbon atoms than starting material, acetic acid high yield. A number minor side-reactions also occur. The mechanisms these processes discussed.
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