Selective Preparation of the [3,5-tBu2-1,2,4-C2P3] Ion and Synthesis and Structure of the Cationic Species nido-[3,5-tBu2-1,2,4-C2P3], Isoelectronic with [C5R5]

作者： Jason M. Lynam , May C. Copsey , Michael Green , John C. Jeffery , John E. McGrady

DOI: 10.1002/ANIE.200351096

关键词:

摘要: Building pyramids: The first P-C cluster, namely, the novel nido species 2, is readily prepared from 1 (=CtBu), which also an excellent precursor for selective synthesis of anion 3. DFT calculations show that there a switch in global minimum, on introduction three P atoms (CH) into [C5H5]+ ion, cyclic-unsaturated to saturated cage species, such as 2.

参考文章(0)

Selective Preparation of the [3,5-tBu2-1,2,4-C2P3] Ion and Synthesis and Structure of the Cationic Species nido-[3,5-tBu2-1,2,4-C2P3], Isoelectronic with [C5R5]

来源期刊

我的账户

Selective Preparation of the [3,5-tBu2-1,2,4-C2P3] Ion and Synthesis and Structure of the Cationic Species nido-[3,5-tBu2-1,2,4-C2P3], Isoelectronic with [C5R5]

来源期刊

相似文章 10

我的账户