Two-stage heat release in nitromethane/air flame and its impact on laminar flame speed measurement

作者: Mahdi Faghih , Zheng Chen

DOI: 10.1016/J.COMBUSTFLAME.2017.05.013

关键词:

摘要: Abstract In premixed flames of most hydrocarbon fuels, there is only one stage heat release. However, two-stage release occurs in nitromethane/air under certain conditions. this study, numerical simulations were conducted for one-dimensional planar and spherical at different initial temperatures (423∼800 K), pressures (0.5∼10 atm) equivalence ratios (0.5∼1.3). Using the flame, we investigated characteristics identified elementary reactions involved these two stages. It was found that occurrence strongly depends on ratio single-stage very fuel-lean mixture. To demonstrate key second release, modified original chemical mechanism compared results predicted by mechanisms. The to be mainly caused reaction NO+H→N+OH. propagating assessed impact determination laminar flame speed. positive burned gas speed induced shown affect accuracy determined traditional method neglecting using density equilibrium condition. Alternative methods proposed used correct experimental data reported literature.

参考文章(40)
Jenny D. Nauclér, Elna J.K. Nilsson, Alexander A. Konnov, Laminar burning velocity of nitromethane plus air flames: A comparison of flat and spherical flames Combustion and Flame. ,vol. 162, pp. 3803- 3809 ,(2015) , 10.1016/J.COMBUSTFLAME.2015.07.017
E. S. Starkman, Nitroparaffins as Potential Engine Fuel Industrial & Engineering Chemistry. ,vol. 51, pp. 1477- 1480 ,(1959) , 10.1021/IE50600A035
Emilien Varea, Joachim Beeckmann, Heinz Pitsch, Zheng Chen, Bruno Renou, None, Determination of burning velocities from spherically expanding H 2 /air flames Proceedings of the Combustion Institute. ,vol. 35, pp. 711- 719 ,(2015) , 10.1016/J.PROCI.2014.05.137
P. Glarborg, A. B. Bendtsen, J. A. Miller, Nitromethane dissociation: Implications for the CH3 + NO2 reaction International Journal of Chemical Kinetics. ,vol. 31, pp. 591- 602 ,(1999) , 10.1002/(SICI)1097-4601(1999)31:9<591::AID-KIN1>3.0.CO;2-E
A.R. Hall, H.G. Wolfhard, Multiple reaction zones in low pressure flames with ethyl and methyl nitrate, methyl nitrite and nitromethane Symposium (International) on Combustion. ,vol. 6, pp. 190- 199 ,(1957) , 10.1016/S0082-0784(57)80029-0
Kuiwen Zhang, Lidong Zhang, Mingfeng Xie, Lili Ye, Feng Zhang, Peter Glarborg, Fei Qi, An experimental and kinetic modeling study of premixed nitroethane flames at low pressure Proceedings of the Combustion Institute. ,vol. 34, pp. 617- 624 ,(2011) , 10.1016/J.PROCI.2012.06.010
Huangwei Zhang, Peng Guo, Zheng Chen, Critical condition for the ignition of reactant mixture by radical deposition Proceedings of the Combustion Institute. ,vol. 34, pp. 3267- 3275 ,(2013) , 10.1016/J.PROCI.2012.06.035
Weikuo Zhang, Zheng Chen, Wenjun Kong, Effects of diluents on the ignition of premixed H2/air mixtures Combustion and Flame. ,vol. 159, pp. 151- 160 ,(2012) , 10.1016/J.COMBUSTFLAME.2011.05.017
Zhenyu Tian, Lidong Zhang, Yuyang Li, Tao Yuan, Fei Qi, An experimental and kinetic modeling study of a premixed nitromethane flame at low pressure Proceedings of the Combustion Institute. ,vol. 32, pp. 311- 318 ,(2009) , 10.1016/J.PROCI.2008.06.098