Stereochemistry of incorporation of serine into the oxazole ring of virginiamycin M1

作者: Michael B. Purvis , David G. I. Kingston , Nobue Fujii , Heinz G. Floss

DOI: 10.1039/C39870000302

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摘要: Incorportion of serine into the oxazole ring virginiamycin M1 proceeds via (S)-isoemr with loss 3-(pro-S) hydrogen, as deduced from feeding studies various stereospecifically labelled precursors.

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