Stereoselective synthesis of enantiopure condensed [2.2]paracyclophanes
作者： L. Minuti , A. Taticchi , A. Marrocchi , L. Costantini , E. Gacs-Baitz
DOI: 10.1016/S0957-4166(01)00207-5
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摘要: Abstract The Diels–Alder reaction of ( S )-(+)-4-ethenyl[2.2]paracyclophane with 1,4-benzoquinone, N -phenylmaleimide and 3-nitrocyclohexen-1-one has been investigated under atmospheric high pressure conditions. synthesis five optically active [2.2]paracyclophanes containing condensed polycyclic aromatic subunits is described. A structural analysis the products by 1 H 13 C NMR spectroscopy also presented.
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sci-hub.se 参考文章(16)
Aldo Taticchi, Francesco Fringuelli, Dienes in the Diels-Alder reaction ,(1990)
Henning Hopf, Cornelia Mlynek, Sayed El-Tamany, Ludger Ernst, Cyclophane series. Part 24. [2.2](1,4)Phenanthrenoparacyclophane: synthesis and two-dimensional proton and carbon-13 NMR study Journal of the American Chemical Society. ,vol. 107, pp. 6620- 6627 ,(1985) , 10.1021/JA00309A033
E.J. Corey, Herbert Estreicher, 3-Nitrocycloalkenones, synthesis and use as reverse affinity cycloalkynone equivalents Tetrahedron Letters. ,vol. 22, pp. 603- 606 ,(1981) , 10.1016/S0040-4039(01)92500-6
Lucio Minuti, Aldo Taticchi, Eszter Gacs-Baitz, Assunta Marrocchi, Diels-Alder reactions of arylethenes. Synthesis of some [5]phenacenes and fluorenoanthracenes Tetrahedron. ,vol. 54, pp. 10891- 10898 ,(1998) , 10.1016/S0040-4020(98)00642-5
Lucio Minuti, Aldo Taticchi, Eszter Gacs-Baitz, Assunta Marrocchi, High Pressure Diels-Alder Reactions of 2-Vinyl-3,4-Dihydronaphthalene. Synthesis of Cyclopenta[c]- and Indeno[c]Phenanthrenones. Tetrahedron. ,vol. 51, pp. 8953- 8958 ,(1995) , 10.1016/0040-4020(95)00504-2
Lucio Minuti, Aldo Taticchi, Assunta Marrocchi, Eszter Gacs-Baitz, A New Short Route to Hexahelicenes Synthetic Communications. ,vol. 28, pp. 2181- 2190 ,(1998) , 10.1080/00397919808007032
Lucio Minuti, Aldo Taticchi*, Assunta Marrocchi, An improved synthesis of (S)-(+)- and (R)-(−)-4-ethenyl[2.2]paracyclophane Tetrahedron-asymmetry. ,vol. 11, pp. 4221- 4225 ,(2000) , 10.1016/S0957-4166(00)00392-X
René W.M. Aben, Lucio Minuti, Hans W. Scheeren, Aldo Taticchi, High pressure -Lewis acid catalyzed diels-alder reactions of 3-methylcyclohex-2-en-1-one. A straightforward route to cis and Tras angularly methylated octalones. Tetrahedron Letters. ,vol. 32, pp. 6445- 6448 ,(1991) , 10.1016/0040-4039(91)80191-8
Eszter Gacs-Baitz, Lucio Minuti, Aldo Taticchi, A new short synthetic approach to cyclopentaphenanthrenones Tetrahedron. ,vol. 50, pp. 10359- 10366 ,(1994) , 10.1016/S0040-4020(01)81768-3
Francesco Fringuelli, Lucio Minuti, Ferdinando Pizzo, Aldo Taticchi, Giovanni Consiglio, Michel Chanon, Cindy Striley, Johann Weidlein, Ahmad Nasiri, Yoshito Okada, Reactivity and Selectivity in Lewis-Acid-Catalyzed Diels--Alder Reactions of 2-Cyclohexenones. Acta Chemica Scandinavica. ,vol. 47, pp. 255- 263 ,(1993) , 10.3891/ACTA.CHEM.SCAND.47-0255