The structure of rankinite
作者： Isao KUSACHI , Chiyoko HENMI , Akira KAWAHARA , Kitinosuke HENMI
DOI: 10.2465/MINERJ.8.38
关键词:
摘要: The crystal structure of rankinite has been determined by Patterson and direct methods refined to R=11.6%, using a from Fuka, Bitchu-cho, Japan: P21⁄a, 10.60(2), b 8.92(2), c 7.89(2)A, β 119.6(1)°, Z=4 Ca3Si2O7. There are in the arrays Si2O7 groups parallel axis, linked together Ca’s each having seven near oxygen atoms: Ca–O bond length is range 2.25 2.90 A. Si–O 1.52 1.65 structural relationships between (Ca3Si2O7) kilchoanite [Ca6(SiO4)(Si3O10)] described briefly.
rruff.info参考文章(7)
K. M. Moody, The Space-Group and Cell-Dimensions of Rankinite Mineralogical Magazine. ,vol. 30, pp. 79- 79 ,(1953) , 10.1180/MINMAG.1953.030.220.09
S. O. AGRELL, P. GAY, Kilchoanite, a Polymorph of Rankinite Nature. ,vol. 189, pp. 743- 743 ,(1961) , 10.1038/189743A0
D. M. ROY, J. A. GARD, A. W. NICOL, H. F. W. TAYLOR, New Data for the Calcium Silicate, ‘Phase Z’ Nature. ,vol. 188, pp. 1187- 1188 ,(1960) , 10.1038/1881187B0
Philippa M. Black, Rankinite and Kilchoanite from Tokatoka, New Zealand Mineralogical Magazine. ,vol. 37, pp. 517- 519 ,(1969) , 10.1180/MINMAG.1969.037.288.13
H. F. W. Taylor, The Crystal Structure of Kilchoanite, Ca6(SiO4)(Si3O10), with Some Comments on Related Phases Mineralogical Magazine. ,vol. 38, pp. 26- 31 ,(1971) , 10.1180/MINMAG.1971.038.293.03
C. L. Christ, Precision determination of lattice constants of single crystals using the conventional weissenberg camera American Mineralogist. ,vol. 41, pp. 569- 580 ,(1956)
Della M. Roy, Studies in the system CaO-Al2O3-SiO2-H2O IV; Phase equilibria in the high-lime portion of the system CaO-SiO2-H2O American Mineralogist. ,vol. 43, pp. 1009- 1028 ,(1958)