Linking glucose oxidation to luminol-based electrochemiluminescence using bipolar electrochemistry

作者: Vera Eßmann , Daliborka Jambrec , Alexander Kuhn , Wolfgang Schuhmann

DOI: 10.1016/J.ELECOM.2014.11.015

关键词:

摘要: Abstract The range of potential analytes for bipolar electrochemistry can be significantly extended by modification electrodes with enzymatic biosensing layers. In this study, we employed a Prussian blue-based glucose detection system involving electrochemical reduction enzymatically generated hydrogen peroxide at the cathodic pole. concentration in solution correlated oxidative luminol electrochemiluminescence opposite anodic pole, which was recorded photomultiplier tube. This opens route novel analytical systems using oxidase as an amplification element reporter reaction.

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