Solid-State EDLC Device Based on Magnesium Ion-Conducting Biopolymer Composite Membrane Electrolytes: Impedance, Circuit Modeling, Dielectric Properties and Electrochemical Characteristics.
作者： Ahmad SFM Asnawi , Shujahadeen B Aziz , Salah R Saeed , Yuhanees M Yusof , Rebar T Abdulwahid
DOI: 10.3390/MEMBRANES10120389
关键词:
摘要: The polymer electrolyte based on Dx:Cs:Mg(CH3COO)2:Ni with three different glycerol concentrations have been prepared. impedance study has verified that the 42 wt.% of (A3) highest ionic conductivity 7.71 × 10−6 S cm−1 at room temperature. is found to be influenced by transport parameters. From dielectric analysis, it was shown electrolytes in this system obeyed non-Debye behavior. A3 exhibited a dominancy ions (tion > te) breakdown voltage 2.08 V. fabricated electrochemical double layer capacitor (EDLC) achieved specific capacitance values 24.46 F/g and 39.68 via cyclic voltammetry (CV) curve charge–discharge profile, respectively. other significant parameters evaluate performance EDLC determined, such as internal resistance (186.80 202.27 Ω) energy density (4.46 Wh/kg), power (500.58 558.57 W/kg) efficiency (92.88%).
mdpi.com
sci-hub.st 参考文章(74)
Wendy G. Pell, Brian E. Conway, Peculiarities and requirements of asymmetric capacitor devices based on combination of capacitor and battery-type electrodes Journal of Power Sources. ,vol. 136, pp. 334- 345 ,(2004) , 10.1016/J.JPOWSOUR.2004.03.021
M F Z Kadir, A K Arof, Application of PVA–chitosan blend polymer electrolyte membrane in electrical double layer capacitor Materials Research Innovations. ,vol. 15, ,(2011) , 10.1179/143307511X13031890749299
N.H. Zainol, Zurina Osman, Lisani Othman, K.B. Md. Isa, Transport and Morphological Properties of Gel Polymer Electrolytes Containing Mg(CF3SO3)2 Advanced Materials Research. ,vol. 686, pp. 137- 144 ,(2013) , 10.4028/WWW.SCIENTIFIC.NET/AMR.686.137
Nadir Naveed Siddiqui, Afsheen Aman, Alba Silipo, Shah Ali Ul Qader, Antonio Molinaro, Structural analysis and characterization of dextran produced by wild and mutant strains of Leuconostoc mesenteroides. Carbohydrate Polymers. ,vol. 99, pp. 331- 338 ,(2014) , 10.1016/J.CARBPOL.2013.08.004
M.Z.A. Yahya, A.K. Arof, Effect of oleic acid plasticizer on chitosan–lithium acetate solid polymer electrolytes European Polymer Journal. ,vol. 39, pp. 897- 902 ,(2003) , 10.1016/S0014-3057(02)00355-5
N. H. Idris, H. B. Senin, A. K. Arof, Dielectric spectra of LiTFSI-doped chitosan/PEO blends Ionics. ,vol. 13, pp. 213- 217 ,(2007) , 10.1007/S11581-007-0093-Z
T. Tooming, T. Thomberg, H. Kurig, A. Jänes, E. Lust, High power density supercapacitors based on the carbon dioxide activated d-glucose derived carbon electrodes and 1-ethyl-3-methylimidazolium tetrafluoroborate ionic liquid Journal of Power Sources. ,vol. 280, pp. 667- 677 ,(2015) , 10.1016/J.JPOWSOUR.2015.01.157
David K. Lee, Harry R. Allcock, The effects of cations and anions on the ionic conductivity of poly[bis(2-(2-methoxyethoxy)ethoxy)phosphazene] doped with lithium and magnesium salts of trifluoromethanesulfonate and bis (trifluoromethanesulfonyl)imidate Solid State Ionics. ,vol. 181, pp. 1721- 1726 ,(2010) , 10.1016/J.SSI.2010.09.051
K Ramly, M I N Isa, A S A Khiar, Conductivity and dielectric behaviour studies of starch/PEO+x wt-%NH4NO3 polymer electrolyte Materials Research Innovations. ,vol. 15, ,(2011) , 10.1179/143307511X1303189074
Mary Helen Palmuti Braga Vettori, Sandra Mara Martins Franchetti, Jonas Contiero, Structural characterization of a new dextran with a low degree of branching produced by Leuconostoc mesenteroides FT045B dextransucrase Carbohydrate Polymers. ,vol. 88, pp. 1440- 1444 ,(2012) , 10.1016/J.CARBPOL.2012.02.048