New lanthanide-nitrogen bond-valence parameters.
作者： Agata Trzesowska , Rafal Kruszynski , Tadeusz J. Bartczak
DOI: 10.1107/S0108768105016083
关键词:
摘要: The bond-valence parameters (R(ij)), which connect bond valences and lengths, have been computed for lanthanide-nitrogen bonds. It has found that values of decrease with increasing lanthanide atomic number in coordination compounds, they are smaller than the R(ij) inorganic compounds. As expected, larger lanthanide-oxygen parameters. There no obvious dependencies between N atoms sphere parameter value.
sci-hub.se 参考文章(41)
Janet R. Morrow, Lisa A. Buttrey, Valerie M. Shelton, Kristin A. Berback, Efficient catalytic cleavage of RNA by lanthanide(III) macrocyclic complexes: toward synthetic nucleases for in vivo applications Journal of the American Chemical Society. ,vol. 114, pp. 1903- 1905 ,(1992) , 10.1021/JA00031A067
Reed M. Izatt, Jerald S. Bradshaw, Steven A. Nielsen, John D. Lamb, James J. Christensen, Debabrata Sen, Thermodynamic and kinetic data for cation-macrocycle interaction Chemical Reviews. ,vol. 85, pp. 271- 339 ,(1985) , 10.1021/CR00068A003
J.A. Peters, J. Huskens, D.J. Raber, Lanthanide induced shifts and relaxation rate enhancements Progress in Nuclear Magnetic Resonance Spectroscopy. ,vol. 28, pp. 283- 350 ,(1996) , 10.1016/0079-6565(95)01026-2
Rhett Kempe, Elmar Kessenich, Axel Schulz, [Me3SiN(PPh3)·ICN]: A New Labile Donor−Acceptor Complex Inorganic Chemistry. ,vol. 40, pp. 5182- 5187 ,(2001) , 10.1021/IC0102687
Erik D. Brady, David L. Clark, John C. Gordon, P. Jeffrey Hay, D. Webster Keogh, Rinaldo Poli, Brian L. Scott, John G. Watkin, Tris(bis(trimethylsilyl)amido)samarium: X-ray structure and DFT study. Inorganic Chemistry. ,vol. 42, pp. 6682- 6690 ,(2003) , 10.1021/IC0341690
Zuowei Xie, Zhixian Liu, Qingchuan Yang, Thomas C. W. Mak, exo-nido- versus closo-Lanthanacarboranes. Synthesis and Structure of exo-nido-[(C6H5CH2)2C2B10H10]Ln(DME)3, [exo-nido-{(C6H5CH2)2C2B9H9}Ln(THF)3]2 (Ln = Sm, Yb), and closo-exo-[(C6H5CH2)2C2B10H10]4Sm2Na3 Organometallics. ,vol. 18, pp. 3603- 3609 ,(1999) , 10.1021/OM990204S
Richard M. Wood, Khalil A. Abboud, Ruth C. Palenik, Gus J. Palenik, Bond Valence Sums in Coordination Chemistry. Calculation of the Oxidation State of Chromium in Complexes Containing Only Cr−O Bonds and a Redetermination of the Crystal Structure of Potassium Tetra(peroxo)chromate(V) Inorganic Chemistry. ,vol. 39, pp. 2065- 2068 ,(2000) , 10.1021/IC990982C
Charles C. Fuller, David K. Molzahn, Robert A. Jacobson, Crystal and molecular structure of the decacoordinate compound ((hydroxyethyl)ethylenediaminetriacetato)diaquolanthanum(III) trihydrate Inorganic Chemistry. ,vol. 17, pp. 2138- 2143 ,(1978) , 10.1021/IC50186A020
T. Don Tilley, Richard A. Andersen, Allan Zalkin, Tertiary phosphine complexes of the f-block metals. Crystal structure of Yb[N(SiMe3)2]2[Me2PCH2CH2PMe2]: evidence for a ytterbium-.gamma.-carbon interaction Journal of the American Chemical Society. ,vol. 104, pp. 3725- 3727 ,(1982) , 10.1021/JA00377A033
V. S. Urusov, I. P. Orlov, State-of-art and perspectives of the bond-valence model in inorganic crystal chemistry Crystallography Reports. ,vol. 44, pp. 686- 709 ,(1999)