Surface modification of montmorillonite on surface Acid-base characteristics of clay and thermal stability of epoxy/clay nanocomposites.
作者： Soo-Jin Park , Dong-Il Seo , Jae-Rock Lee
关键词:
摘要: Abstract In this work, the effect of surface treatments on smectitic clay was investigated in energetics and thermal behaviors epoxy/clay nanocomposites. The pH values, X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR) were used to analyze cation exchange exfoliation phenomenon interlayer. properties nanocomposites contact angles thermogravimetric analysis (TGA), respectively. From experimental results, modification by dodecylammonium chloride led increases both distance between silicate layers about 8 A acid as well electron acceptor component (γ + s ) free energy, resulting improved interfacial adhesion basic (or donor) epoxy resins acidic (electron acceptor) interlayers. Also, stability highly superior pure resin due presence well-dispersed nanolayer, which has a barrier property composite system.
harvard.edu
elsevier.com
sci-hub.se 参考文章(29)
A. Akelah, A. Moet, Polymer-clay nanocomposites: Free-radical grafting of polystyrene on to organophilic montmorillonite interlayers Journal of Materials Science. ,vol. 31, pp. 3589- 3596 ,(1996) , 10.1007/BF00360767
Soo-Jin Park, Min-Seok Cho, Thermal stability of carbon-MoSi2-carbon composites by thermogravimetric analysis Journal of Materials Science. ,vol. 35, pp. 3525- 3527 ,(2000) , 10.1023/A:1004849110311
T-K Chen, Y-I Tien, K-H Wei, Synthesis and characterization of novel segmented polyurethane/clay nanocomposites Polymer. ,vol. 41, pp. 1345- 1353 ,(2000) , 10.1016/S0032-3861(99)00280-3
J Panzer, Components of solid surface free energy from wetting measurements Journal of Colloid and Interface Science. ,vol. 44, pp. 142- 161 ,(1973) , 10.1016/0021-9797(73)90201-4
Ruijian Xu, Evangelos Manias, Alan J. Snyder, James Runt, New Biomedical Poly(urethane urea)−Layered Silicate Nanocomposites Macromolecules. ,vol. 34, pp. 337- 339 ,(2001) , 10.1021/MA0013657
Anatoly Kim, Soo-Jin Park, Jae-Rock Lee, Stabilization of Liquid Crystal-in-Water Dispersion with Polymer/Surfactant Mixture: Nematic Curvilinear Aligned Phase Composite Film Journal of Colloid and Interface Science. ,vol. 197, pp. 119- 125 ,(1998) , 10.1006/JCIS.1997.5208
J.W Cho, D.R Paul, Nylon 6 nanocomposites by melt compounding Polymer. ,vol. 42, pp. 1083- 1094 ,(2001) , 10.1016/S0032-3861(00)00380-3
Tie Lan, Padmananda D. Kaviratna, Thomas J. Pinnavaia, Epoxy self-polymerization in smectite clays Journal of Physics and Chemistry of Solids. ,vol. 57, pp. 1005- 1010 ,(1996) , 10.1016/0022-3697(95)00388-6
H. H. Horowitz, Gershon. Metzger, A New Analysis of Thermogravimetric Traces. Analytical Chemistry. ,vol. 35, pp. 1464- 1468 ,(1963) , 10.1021/AC60203A013
T Agag, Polybenzoxazine–montmorillonite hybrid nanocomposites: synthesis and characterization Polymer. ,vol. 41, pp. 7083- 7090 ,(2000) , 10.1016/S0032-3861(00)00064-1