Theoretical study of the recently observed 3Πg state of the F2 molecule

作者: T Sakai , K Tanaka , A Murakami , H Iwaki , H Terashima

DOI: 10.1088/0953-4075/21/2/007

关键词:

摘要: An ab initio theoretical investigation is carried out mainly on the 3 Pi g state of fluorine molecule (F2). Results support assignment new triplet observed by Hoshiba and co-workers (1985) as g. A possibility concerning laser transition u from system discussed.

参考文章(25)
K Hoshiba, Y Fujita, S S Kano, H Takuma, T Takayanagi, K Wakiya, H Suzuki, Experimental observation of the F2 VUV laser levels Journal of Physics B. ,vol. 18, ,(1985) , 10.1088/0022-3700/18/24/009
Hiroyuki Nishimura, David C. Cartwright, Sandor Trajmar, Electron energy‐loss spectra in molecular fluorine Journal of Chemical Physics. ,vol. 71, pp. 5039- 5041 ,(1979) , 10.1063/1.438275
G. Das, Arnold C. Wahl, Theoretical Study of the F2 Molecule Using the Method of Optimized Valence Configurations Journal of Chemical Physics. ,vol. 56, pp. 3532- 3540 ,(1972) , 10.1063/1.1677728
R.‐G. Wang, Z.‐W. Wang, M. A. Dillon, David Spence, Electron energy loss spectroscopy of molecular fluorine Journal of Chemical Physics. ,vol. 80, pp. 3574- 3579 ,(1984) , 10.1063/1.447177
William D. Laidig, Paul Saxe, Rodney J. Bartlett, The description of N2 and F2 potential energy surfaces using multireference coupled cluster theory Journal of Chemical Physics. ,vol. 86, pp. 887- 907 ,(1987) , 10.1063/1.452291
Joseph R. Woodworth, James K. Rice, An efficient, high‐power F2 laser near 157 nm Journal of Chemical Physics. ,vol. 69, pp. 2500- 2504 ,(1978) , 10.1063/1.436892
Sigrid D. Peyerimhoff, Robert J. Buenker, Electronically excited and ionized states of the chlorine molecule principles and practice of constraint programming. ,vol. 57, pp. 279- 296 ,(1981) , 10.1016/0301-0104(81)80208-X
A. Kay Hays, Joseph R. Woodworth, James K. Rice, vuv emissions from mixtures of F2and the noble gases—A molecular F2laser at 1575 Å Applied Physics Letters. ,vol. 31, pp. 31- 33 ,(1977) , 10.1063/1.89467
David C. Cartwright, P. Jeffrey Hay, Theoretical studies of the valence electronic states and the 1Πu←X1Σ+g absorption spectrum of the F2 molecule Journal of Chemical Physics. ,vol. 70, pp. 3191- 3203 ,(1979) , 10.1063/1.437907