On the Synthesis Conditions of N and N2 Endohedral Fullerenes
作者： Seitaro Ito , Hidekazu Shimotani , Hidenori Takagi , Nita Dragoe
DOI: 10.1080/15363830802064187
关键词:
摘要: Abstract The glow discharge at low pressure, under nitrogen atmosphere, is an easy method to synthesize encapsulated fullerenes. We present here the results concerning our attempts optimize synthesis conditions by this as well basic characterization of obtained products, namely N@C60 and N@C70 together with molecular counterparts N2@C60 N2@C70. Changes in voltage temperature indicated optimum yield for case, which was about 0.0025%, 650°C, 1 Torr, 850 V 2 mA discharge. In paper we discuss HPLC separation these products behavior N2 C60 cage.
harvard.edu
elsevier.com
sci-hub.se 参考文章(26)
A. Weidinger, M. Waiblinger, B. Pietzak, T. Almeida Murphy, Atomic nitrogen in C 60 :N@C 60 Applied Physics A: Materials Science & Processing. ,vol. 66, pp. 287- 292 ,(1998) , 10.1007/S003390050668
Hideyuki Funasaka, Koji Sakurai, Yoshihiro Oda, Kazunori Yamamoto, Takeshi Takahashi, Magnetic properties of Gd@C82 metallofullerene Chemical Physics Letters. ,vol. 232, pp. 273- 277 ,(1995) , 10.1016/0009-2614(95)90631-2
B. Goedde, P. Jakes, M. Waiblinger, K.-P. Dinse, A. Weidinger, CHROMATOGRAPHIC SEPARATION OF N@C60/C60 AND N@C70/C70 MIXTURES Fullerene Science and Technology. ,vol. 9, pp. 329- 337 ,(2001) , 10.1081/FST-100104497
Jerzy Cioslowski, Endohedral chemistry: electronic structures of molecules trapped inside the C60 cage Journal of the American Chemical Society. ,vol. 113, pp. 4139- 4141 ,(1991) , 10.1021/JA00011A013
C. Knapp, N. Weiden, H. Kass, K.-P. Dinse, B. Pietzak, M. Waiblinger, A. Weidinger, Electron paramagnetic resonance study of atomic phosphorus encapsulated in [60]fullerene Molecular Physics. ,vol. 95, pp. 999- 1004 ,(1998) , 10.1080/00268979809483233
T. Almeida Murphy, Th. Pawlik, A. Weidinger, M. Höhne, R. Alcala, J.-M. Spaeth, Observation of Atomlike Nitrogen in Nitrogen-Implanted Solid C 60 Physical Review Letters. ,vol. 77, pp. 1075- 1078 ,(1996) , 10.1103/PHYSREVLETT.77.1075
L. Franco, S. Ceola, C. Corvaja, S. Bolzonella, W. Harneit, M. Maggini, Synthesis and magnetic properties of N@C60 derivatives Chemical Physics Letters. ,vol. 422, pp. 100- 105 ,(2006) , 10.1016/J.CPLETT.2006.02.046
Harald Mauser, Andreas Hirsch, Nicolaas J. R. van Eikema Hommes, Timothy Clark, Björn Pietzak, Alois Weidinger, Lothar Dunsch, Stabilization of Atomic Nitrogen Inside C60 Angewandte Chemie International Edition in English. ,vol. 36, pp. 2835- 2838 ,(1997) , 10.1002/ANIE.199728351
M. Saunders, R. J. Cross, H. A. Jimenez-Vazquez, R. Shimshi, A. Khong, Noble Gas Atoms Inside Fullerenes Science. ,vol. 271, pp. 1693- 1697 ,(1996) , 10.1126/SCIENCE.271.5256.1693
Hisanori Shinohara, Masayasu Inakuma, Naohiro Hayashi, Hiroyasu Sato, Yahachi Saito, Tatsuhisa Kato, Shunji Bandow, Spectroscopic Properties of Isolated Sc3@C82 Metallofullerene The Journal of Physical Chemistry. ,vol. 98, pp. 8597- 8599 ,(1994) , 10.1021/J100086A001