Synthesis and characterization of fluorescent-active triazole-gold complexes
作者： Boliang Dong , Yijin Su , Xiaohan Ye , Jeffrey L. Petersen , Xiaodong Shi
DOI: 10.1007/S11426-015-5412-Z
关键词:
摘要: Fluorescence active fused-triazole was developed as a ligand in gold(I) cation coordination. The coordination ability evaluated using NMR and fluorescence emission. Our previously reported N-2-aryl-triazoles, though gave good emission, could not form stable complexes with gold cations. A new N-fused-triazole (NFT) derivative prepared the indicated formed strong Both complex were characterized by X-ray crystallography. properties of various (with different primary ligands) evaluated, which suggested feasibility emission potential tools for future mechanistic investigation.
springer.com
sci-hub.se 参考文章(17)
Savarimuthu Philip Anthony, Organic Solid‐State Fluorescence: Strategies for Generating Switchable and Tunable Fluorescent Materials ChemPlusChem. ,vol. 77, pp. 518- 531 ,(2012) , 10.1002/CPLU.201200073
Filip Teplý, Photoredox catalysis by [Ru(bpy)3]2+ to trigger transformations of organic molecules. Organic synthesis using visible-light photocatalysis and its 20th century roots Collection of Czechoslovak Chemical Communications. ,vol. 76, pp. 859- 917 ,(2011) , 10.1135/CCCC2011078
Haifeng Duan, Sujata Sengupta, Jeffrey L. Petersen, Xiaodong Shi, Synthesis and Characterization of NH-triazole-Bound Rhodium(I) Complexes: Substituted-Group-Controlled Regioselective Coordination Organometallics. ,vol. 28, pp. 2352- 2355 ,(2009) , 10.1021/OM8011163
Kyle P. Carter, Alexandra M. Young, Amy E. Palmer, Fluorescent Sensors for Measuring Metal Ions in Living Systems Chemical Reviews. ,vol. 114, pp. 4564- 4601 ,(2014) , 10.1021/CR400546E
Christoph Ulbricht, Beatrice Beyer, Christian Friebe, Andreas Winter, Ulrich S. Schubert, Recent Developments in the Application of Phosphorescent Iridium(III) Complex Systems Advanced Materials. ,vol. 21, pp. 4418- 4441 ,(2009) , 10.1002/ADMA.200803537
Yuxiu Liu, Wuming Yan, Yunfeng Chen, Jeffrey L. Petersen, Xiaodong Shi, Efficient synthesis of N-2-aryl-1,2,3-triazole fluorophores via post-triazole arylation. Organic Letters. ,vol. 10, pp. 5389- 5392 ,(2008) , 10.1021/OL802246Q
David J. Gorin, Benjamin D. Sherry, F. Dean Toste, Ligand Effects in Homogeneous Au Catalysis Chemical Reviews. ,vol. 108, pp. 3351- 3378 ,(2008) , 10.1021/CR068430G
Xiaohan Ye, Zhengrong He, Tonia Ahmed, Keith Weise, Novruz G. Akhmedov, Jeffrey L. Petersen, Xiaodong Shi, 1,2,3-Triazoles as versatile directing group for selective sp2 and sp3 C–H activation: cyclization vs substitution Chemical Science. ,vol. 4, pp. 3712- 3716 ,(2013) , 10.1039/C3SC51211H
Haifeng Duan, Sujata Sengupta, Jeffrey L. Petersen, Novruz G. Akhmedov, Xiaodong Shi, Triazole−Au(I) Complexes: A New Class of Catalysts with Improved Thermal Stability and Reactivity for Intermolecular Alkyne Hydroamination Journal of the American Chemical Society. ,vol. 131, pp. 12100- 12102 ,(2009) , 10.1021/JA9041093
Elizabeth M. Nolan, Stephen J. Lippard, Small-molecule fluorescent sensors for investigating zinc metalloneurochemistry. Accounts of Chemical Research. ,vol. 42, pp. 193- 203 ,(2009) , 10.1021/AR8001409