Microwave l-type resonance transitions of the v6 = 1 state in CHF3 and CDF3: Accidental degeneracy and molecular structure
作者： Yoshiyuki Kawashima , A.Peter Cox
DOI: 10.1016/0022-2852(78)90140-6
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摘要: Abstract Observations of the direct l -type resonance transitions in microwave spectrum v 6 = 1 state CHF 3 and CDF have been extended to J 37. Accidental degeneracies were found between 34, K 0 both molecules enabling C rotational constants be determined, using 118 observed frequencies for 104 . After suitable correction B used determine r , 2 e structures The equilibrium structure was determined CH 1.091 ± 0.014 A CF 1.3284 0.0031 ∠FCF 108.58 0.34°.
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